630233
1-(Phenylsulfinyl)piperidine
97%
Synonym(s):
1-Benzenesulfinylpiperidine
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About This Item
Empirical Formula (Hill Notation):
C11H15NOS
CAS Number:
Molecular Weight:
209.31
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
mp
84-88 °C (lit.)
storage temp.
−20°C
SMILES string
O=S(N1CCCCC1)c2ccccc2
InChI
1S/C11H15NOS/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1,3-4,7-8H,2,5-6,9-10H2
InChI key
LBRJCAJLGAXDKP-UHFFFAOYSA-N
Application
Reagent for:
Reagent for synthesis of:
- Selective glycosylation
- Mannopyranolsylations
- Design of enzyme stabilizers
Reagent for synthesis of:
- Glycan array for affinity studies with influenza hemagglutinins†
- Orthogonal protecting groups for preparation of highly branched oligosaccharides
- Tetrasaccharide repeating units related to E. Coli 78 O-antigenic polysaccharides
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Flavia Izzo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(60), 15189-15193 (2017-08-24)
Unprotected tertiary sulfonimidamides have been prepared in good to excellent yields in a one-pot transformation from tertiary sulfinamides through NH transfer. The reaction is mediated by commercially available (diacetoxyiodo)benzene and ammonium carbamate in methanol under convenient conditions. A wide range
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