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Sigma-Aldrich

Tetraamminepalladium(II) chloride monohydrate

98%

Synonym(s):

Tetraamminepalladium(2+) dichloride monohydrate

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About This Item

Linear Formula:
Pd(NH3)4Cl2·H2O
CAS Number:
Molecular Weight:
263.46
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

120 °C (dec.) (lit.)

density

1.91 g/mL at 25 °C (lit.)

SMILES string

N.N.N.N.O.Cl[Pd]Cl

InChI

1S/2ClH.4H3N.H2O.Pd/h2*1H;4*1H3;1H2;/q;;;;;;;+2/p-2

InChI key

WVCXSPJPERKPJS-UHFFFAOYSA-L

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General description

Tetraamminepalladium (II) chloride monohydrate is a coordination complex that is used as a catalyst and as a precursor to synthesize other palladium compounds.

Application

Tetraamminepalladium(II) chloride monohydrate can be used as a precursor in the synthesis of Pd (II) complex that is immobilized on hydrophilic graphite oxide for its use as a catalyst in the Heck coupling reaction.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Immobilization of a Pd (II) complex on hydrophilic graphite oxide and its catalytic investigation in the Heck coupling reaction
Mastalir A, et al.
Applied Organometallic Chemistry, 34(4), e5565-e5565 (2020)
The use of graphite oxide to produce mesoporous carbon supporting Pt, Ru, or Pd nanoparticles
Gotoh K, et al.
Carbon, 47(8), 2120-2214 (2009)
Surface engineering of a supported PdAg catalyst for hydrogenation of CO2 to formic acid: elucidating the active Pd atoms in alloy nanoparticles
Mori K, et al.
Journal of the American Chemical Society, 140(28), 8902-8909 (2018)

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