12902

Potassium hexacyanocobaltate(III)

≥97.0%

• Synonim(y): Tripotassium hexacyanocobaltate(III)
• Wzór liniowy: K₃Co(CN)₆
• Numer CAS: 13963-58-1
• Masa cząsteczkowa: 332.33
• NACRES: NA.55
• PubChem Substance ID: 329749935
• UNSPSC Code: 12352202
• EC Number: 237-742-1
• MDL number: MFCD00011391
• Assay: ≥97.0%
• Form: crystalline

Właściwości

• Quality Segment: 100
• assay: ≥97.0%
• form: crystalline
• reaction suitability: reagent type: catalyst; core: cobalt
• impurities: ≤0.1% free cyanide
• density: 1.878 g/mL at 25 °C (lit.)
• anion traces: sulfate (SO₄^2-): ≤500 mg/kg
• cation traces: Fe: ≤50 mg/kg
• suitability: suitable for acidity or alkalinity (alkalinity <= 0.15 meq/g)
• SMILES string: [K+].[K+].[K+].N#C[Co-3](C#N)(C#N)(C#N)(C#N)C#N
• InChI: 1S/6CN.Co.3K/c6*1-2;;;;/q;;;;;;-3;3*+1
• InChI key: VSUFNKULKBVQQW-UHFFFAOYSA-N

Opis

Application

Potassiumhexacyanocobaltate(III) can be used as a complexing agent to synthesize double metal cyanide catalyst:

• For the chemoselective reductive amination of carbonyl compounds with aromatic amines to synthesize substituted amines in the presence of polymethylhydrosiloxane as a reducing agent.
• In the ring opening polymerization of propylene oxide to synthesize polyols.
• In the coupling reaction of CO₂ with hydrous epoxides to synthesize cyclic carbonates.

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Informacja o środkach bezpieczeństwa

• Klasa składowania: 13 - Non Combustible Solids
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable