900401

SLAP 2,3-Bicyclo-(3,4-THF) N-BnPip Reagent

≥95%

• Synonim(y): trans-N³-Benzyl-N³-((trimethylsilyl)methyl)tetrahydrofuran-3,4-diamine
• Wzór empiryczny (zapis Hilla): C₁₅H₂₆N₂OSi
• Masa cząsteczkowa: 278.47
• NACRES: NA.22
• UNSPSC Code: 12352103

Właściwości

• Quality Segment: 100
• assay: ≥95%
• form: liquid
• refractive index: n/D 1.520
• density: 1.000 g/mL
• functional group: amine, ether, phenyl
• storage temp.: −20°C

Opis

Application

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)₂dtbbpy]PF₆ (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

Other Notes

• Technology Spotlight: SLAP Reagents for Piperazine Synthesis
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
• Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS07
• Słowo ostrzegawcze: Warning
• Kody zagrożeń: H315,H319,H335
• Ostrzeżenia: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Narządy docelowe: Respiratory system
• Klasa składowania: 10 - Combustible liquids
• Co się dzieje?: WGK 3