726192

Bis(4-methylphenyl)iodonium hexafluorophosphate

98%

• Synonim(y): Bis(p-tolyl)iodonium hexafluorophosphate
• Wzór empiryczny (zapis Hilla): C₁₄H₁₄F₆IP
• Numer CAS: 60565-88-0
• Masa cząsteczkowa: 454.13
• UNSPSC Code: 12352300
• NACRES: NA.23
• PubChem Substance ID: 329764214
• EC Number: 262-301-5
• Beilstein/REAXYS Number: 3581445
• MDL number: MFCD06656584

Właściwości

• Quality Segment: 100
• assay: ≥97.5% (TLC), 98%
• form: solid
• SMILES string: F[P-](F)(F)(F)(F)F.Cc1ccc([I+]c2ccc(C)cc2)cc1
• InChI: 1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1
• InChI key: LHLVGWWCRPPKBC-UHFFFAOYSA-N

Opis

General description

Bis(4-methylphenyl)iodonium hexafluorophosphate is a white powder. It melts at 175-180 °C and shows an UV absorption peak at 267nm. 1

Application

• Covalent Functionalisation of Few-Layer Black Phosphorus using Aryl Iodonium Salts and Comparison to Diazonium Modified Black Phosphorus: Explores the functionalization of black phosphorus using bis(4-methylphenyl)iodonium hexafluorophosphate and compares it to diazonium modification (M Van Druenen, 2019).


• Iodonium sulfonates as high‐performance coinitiators and additives for CQ‐based systems: Toward aromatic amine‐free photoinitiating systems: Examines the effectiveness of iodonium sulfonates and bis(4-methylphenyl)iodonium hexafluorophosphate in CQ-based photoinitiating systems (J Kirschner et al., 2019).


• Thiophene-substituted phenothiazine-based photosensitisers for radical and cationic photopolymerization reactions under visible laser beams (405 and 455 nm): Studies the use of thiophene-substituted phenothiazine in combination with bis(4-methylphenyl)iodonium hexafluorophosphate for effective photopolymerization (P Chao et al., 2016).

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS05
• Słowo ostrzegawcze: Danger
• Kody zagrożeń: H314
• Ostrzeżenia: P280 - P305 + P351 + P338 - P310
• Hazard Classifications: Skin Corr. 1B
• Klasa składowania: 8A - Combustible corrosive hazardous materials
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable