If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
Przejdź do
638080
tBuXPhos
98%, solid
Bardziej ekologiczna alternatywa
Synonim(y):
tBuXPhos, 2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl, t-Bu XPhos, tert-Butyl XPhos
Wybierz wielkość
| Rozmiar/SKU | Dostępność | Cena netto |
|---|---|---|
1 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 255,00 zł 191,25 zł |
5 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 816,00 zł 612,00 zł |
25 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 3890,00 zł 2917,50 zł |
100 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 7100,00 zł 5325,00 zł |
500 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 32 660,00 zł |
Informacje o tej pozycji
191,25 zł
Cena katalogowa255,00 złZaoszczędź 25%Nazwa produktu
tBuXPhos, 98%
Quality Segment
product line
Buchwald Ligand
assay
98%
form
solid
reaction suitability
reaction type: Cross Couplings, reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Carboxylations, reagent type: ligand
reaction type: Decarboxylations
greener alternative product score
old score: 12
new score: 1
Find out more about DOZN™ Scoring
greener alternative product characteristics
Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
148-151 °C (lit.)
functional group
phosphine
greener alternative category
SMILES string
CC(P(C(C=CC=C1)=C1C(C(C(C)C)=CC(C(C)C)=C2)=C2C(C)C)C(C)(C)C)(C)C
InChI
1S/C29H45P/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12/h13-21H,1-12H3
InChI key
SACNIGZYDTUHKB-UHFFFAOYSA-N
General description
Learn more about Buchwald Phosphine Ligands
Application
It can be used in the following reactions:
- Palladium-catalyzed Tsuji-Trost substitution and cross-coupling of benzylic fluorides.
- Palladium-catalyzed C-N cross-coupling of sulfinamides and aryl halides.
- Palladium-catalyzed rapid methoxylation and deuteriomethoxylation of bromo-chalcones.
Legal Information
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Ta pozycja | |||
|---|---|---|---|
| description 98% | description ≥98%, ISOM8™ | description - | description 98% |
| assay 98% | assay ≥98% | assay - | assay 98% |
| reaction suitability reagent type: ligand | reaction suitability reaction type: Cross Couplings, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand, reaction type: Carboxylations, reaction type: Decarboxylations, reaction type: Arylations | reaction suitability reagent type: ligand | reaction suitability reagent type: ligand |
| functional group phosphine | functional group phosphine | functional group - | functional group phosphine |
| form solid | form solid | form solid | form - |
| Quality Level 300 | Quality Level 300 | Quality Level 100 | Quality Level 300 |
| mp 148-151 °C (lit.) | mp 148-151 °C (lit.), 144-145 °C (Lit.) | mp - | mp 164-166 °C (lit.) |
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Klasa składowania
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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