474789

(S)-(−)-Glycidol

97%, optical purity ee: 98% (GLC)

• Synonim(y): (S)-(−)-2,3-Epoxy-1-propanol, (S)-(−)-Oxirane-2-methanol
• Wzór empiryczny (zapis Hilla): C₃H₆O₂
• Numer CAS: 60456-23-7
• Masa cząsteczkowa: 74.08
• UNSPSC Code: 12352005
• NACRES: NA.22
• PubChem Substance ID: 24871051
• MDL number: MFCD00074874
• Beilstein/REAXYS Number: 79783
• Assay: 97%

Właściwości

• assay: 97%
• optical activity: [α]20/D −15°, neat
• optical purity: ee: 98% (GLC)
• refractive index: n20/D 1.433 (lit.)
• bp: 66-67 °C/19 mmHg (lit.)
• density: 1.116 g/mL at 20 °C (lit.)
• functional group: ether, hydroxyl
• storage temp.: −20°C
• SMILES string: OC[C@H]1CO1
• InChI: 1S/C3H6O2/c4-1-3-2-5-3/h3-4H,1-2H2/t3-/m0/s1
• InChI key: CTKINSOISVBQLD-VKHMYHEASA-N

Opis

General description

Glycidol or 2,3-epoxy-1-propanol is a highly reactive epoxy derivative, which is generally used as a monomer in the preparation of many polymers like polyesters, polycarbonates, polyurethanes, and polyamides. It is also used in the preparation of detergents, rubbers, perfumes, fabric dyes, varnishes, cosmetics, and paints.

Application

Employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis.

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS06,GHS08
• Słowo ostrzegawcze: Danger
• Kody zagrożeń: H302 + H312,H315,H319,H330,H335,H341,H350,H360F
• Ostrzeżenia: P202 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
• Narządy docelowe: Respiratory system
• Klasa składowania: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): 161.6 °F
• Temperatura zapłonu (°C): 72 °C
• PPE (środki ochrony indywidualnej): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter