437867

Copper(II) bromide

99.999% trace metals basis

• Synonim(y): Cupric bromide
• Wzór liniowy: CuBr₂
• Numer CAS: 7789-45-9
• Masa cząsteczkowa: 223.35
• NACRES: NA.23
• PubChem Substance ID: 24867403
• UNSPSC Code: 12352302
• EC Number: 232-167-2
• MDL number: MFCD00010970
• Assay: 99.999% trace metals basis
• Form: solid

Właściwości

• Quality Segment: 100
• assay: 99.999% trace metals basis
• form: solid
• reaction suitability: core: copper
• impurities: ≤15.0 ppm Trace Metal Analysis
• mp: 498 °C (lit.)
• density: 4.77 g/mL at 25 °C (lit.)
• SMILES string: Br[Cu]Br
• InChI: 1S/2BrH.Cu/h2*1H;/q;;+2/p-2
• InChI key: QTMDXZNDVAMKGV-UHFFFAOYSA-L

Opis

General description

Copper bromide is a monoclinic crystalline material. It is soluble in water, alcohol and acetone. It may be synthesized by neutralizing oxides, carbonates or hydroxides of copper with hydrobromic acid. Another synthesis technique is by oxidizing copper either with bromine water or bromine solutions in alcohol.

Application

Copper bromide may be used as a catalyst in organic reactions and as a brominating agent. Copper catalyzed biotinylation of acetylene terminated poly(ethylene glycol) methyl ether methylacrylate (PEGMEMA) chains has been investigated. Copper dibromide in acetonitrile acts as a catalyst in the interconversion of acetals to bis(methoxyphenyl)methyl (BMPM) ethers. It has been used as a catalyst in the intramolecular decarboxylative functionalization of α-carbonyl to yield a C(sp(3))-O bond for the synthesis of furo[3,2-c]coumarins. Poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been reportedly doped with CuBr₂ to act as hole transport layer (HTL) in polymer solar cells(PSCs). Doping increase the conductivity and thereby increasing the device power conversion efficiency of PSCs.

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS05,GHS07,GHS09
• Słowo ostrzegawcze: Danger
• Kody zagrożeń: H302,H314,H410
• Ostrzeżenia: P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
• Klasa składowania: 8A - Combustible corrosive hazardous materials
• Co się dzieje?: WGK 3
• PPE (środki ochrony indywidualnej): Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges