358924

(+)-O,O′-Diacetyl-L-tartaric anhydride

97%

• Synonim(y): (+)-Diacetyl-L-tartaric anhydride
• Wzór empiryczny (zapis Hilla): C₈H₈O₇
• Numer CAS: 6283-74-5
• Masa cząsteczkowa: 216.14
• UNSPSC Code: 12352005
• NACRES: NA.22
• PubChem Substance ID: 24862037
• EC Number: 228-502-7
• Beilstein/REAXYS Number: 87315
• MDL number: MFCD00037918
• Assay: 97%

Właściwości

• Quality Segment: 100
• assay: 97%
• optical activity: [α]20/D +59°, c = 6 in acetone
• mp: 130-135 °C (lit.)
• functional group: anhydride, ester
• storage temp.: 2-8°C
• SMILES string: CC(=O)O[C@@H]1[C@@H](OC(C)=O)C(=O)OC1=O
• InChI: 1S/C8H8O7/c1-3(9)13-5-6(14-4(2)10)8(12)15-7(5)11/h5-6H,1-2H3/t5-,6-/m1/s1
• InChI key: XAKITKDHDMPGPW-PHDIDXHHSA-N

Opis

General description

(+)-O,O′-Diacetyl-L-tartaric anhydride is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed as a reagent for the chiral derivatization of amino alcohols. It also reacts with alkanoamines in aprotic medium containing trichloroacetic acid and produces tartaric acid monoesters.

Application

(+)-O,O′-Diacetyl-L-tartaric anhydride may be used as a chiral derivatizating agent in the following:

• determination of enantiomeric vigabatrin in mouse serum samples using ultra-high performance liquid chromatography-quadrupole-time-of-flight mass spectrometry (UHPLC-Q-TOF-M)        
• determination of trantinterol in rat plasma by ultra performance liquid chromatography–electrospray ionization mass spectrometry (UPLC–MS/MS)

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Informacja o środkach bezpieczeństwa

• Klasa składowania: 11 - Combustible Solids
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• PPE (środki ochrony indywidualnej): dust mask type N95 (US), Eyeshields, Gloves