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Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

solid

Synonim(y):

NSC 307191, Palladium(II) tetrafluoroborate tetraacetonitrile complex

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Do Państwa/SKUDostępnośćCena netto
250 mg
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357,00 zł
1 g
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1260,00 zł

Informacje o tej pozycji

Wzór liniowy:
Pd(CH3CN)4(BF4)2
Numer CAS:
Masa cząsteczkowa:
444.24
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

357,00 zł


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Nazwa produktu

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate,

form

solid

Quality Segment

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium, reagent type: ligand

mp

230 °C (dec.) (lit.)

SMILES string

[Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F

InChI

1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2

InChI key

YWMRPVUMBTVUEX-UHFFFAOYSA-N

General description

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:
  • Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands

Precursor for:
  • Synthesis of dendritic SCS-pincer palladium complexes
  • Palladium complexes of click ligands
  • Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
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description

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description

99.99%

description

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description

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reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Stille Coupling, reagent type: catalyst
core: palladium, reagent type: ligand, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Cross Couplings, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reagent type: catalyst, reaction type: Negishi Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Stille Coupling

reaction suitability

reaction type: Sonogashira Coupling, reagent type: ligand, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
core: palladium, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Cross Couplings, reaction type: Negishi Coupling

reaction suitability

reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, core: palladium, reaction type: Stille Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling

form

solid

form

powder

form

solid

form

solid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

mp

230 °C (dec.) (lit.)

mp

-

mp

-

mp

-


pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Inhalation

Klasa składowania

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the purity of this chemical? And how much percentage of chloride (Cl-) or bromide ion (Br-) is contented in this chemical?

    1 answer
    1. The purity of this item is not tested for this item. The percentage of Chloride and Bromide is not on the COA and not tested for.

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