13468

2-Phenyl-1,3-dioxan-5-ol

mixture of cis and trans, ≥97.0% (HPLC)

• Synonim(y): 1,3-O-Benzylideneglycerol
• Wzór empiryczny (zapis Hilla): C₁₀H₁₂O₃
• Numer CAS: 1708-40-3
• Masa cząsteczkowa: 180.20
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 57647095
• EC Number: 216-963-7
• Beilstein/REAXYS Number: 84059
• MDL number: MFCD00047504
• Assay: ≥97.0% (HPLC)
• Form: powder

Właściwości

• Quality Segment: 100
• assay: ≥97.0% (HPLC)
• form: powder
• functional group: ether, hydroxyl, phenyl
• storage temp.: 2-8°C
• SMILES string: OC1COC(OC1)c2ccccc2
• InChI: 1S/C10H12O3/c11-9-6-12-10(13-7-9)8-4-2-1-3-5-8/h1-5,9-11H,6-7H2
• InChI key: BWKDAAFSXYPQOS-UHFFFAOYSA-N

Opis

General description

cis-2-phenyl-1,3-dioxan-5-ol reacts with triphenylphosphine-carbon tetrabromide to yield cis-4-bromomethyl-2-phenyl-1,3-dioxolan, its trans-diastereoisomer and trans-5-bromo-2-phenyl-1,3-dioxan.

Application

2-Phenyl-1,3-dioxan-5-ol was used as starting reagent in the synthesis of carbonate of glycerol monomer, 5-benzyloxy-1,3-dioxan-2-one which forms copolymers with ε-caprolactone.

2-Phenyl-1,3-dioxan-5-ol can be used as a starting material in the synthesis of 5-benzyloxy1,3-dioxan-2-one (a carbonate of glycerol monomer). It undergoes ring-opening polymerization with ε-caprolactone in presence of tin(II) 2-ethylhexanoate (Sn(oct)₂).

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Informacja o środkach bezpieczeństwa

• Klasa składowania: 11 - Combustible Solids
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• PPE (środki ochrony indywidualnej): Eyeshields, Gloves, type N95 (US)