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72285

Sigma-Aldrich

Nickel(II) sulfate heptahydrate

purum p.a., crystallized, ≥99.0% (KT)

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About This Item

Linear Formula:
NiSO4 · 7H2O
CAS Number:
Molecular Weight:
280.86
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

purum p.a.

Assay

≥99.0% (KT)

form

crystals

quality

crystallized

density

1.948 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤500 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Na: ≤100 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

[Ni++].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-]S([O-])(=O)=O

InChI

1S/Ni.H2O4S.7H2O/c;1-5(2,3)4;;;;;;;/h;(H2,1,2,3,4);7*1H2/q+2;;;;;;;;/p-2

InChI key

OGKAGKFVPCOHQW-UHFFFAOYSA-L

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General description

Nickel(II) sulfate hexahydrate is a hydrated nickel salt. Its thermal decomposition in the presence of air and helium has been studied. Its crystals exist in monoclinic and tetragonal polymorphic forms.

Application

Nickel(II) sulfate hexahydrate may be used in the preparation of NiFe2O4 nanoparticles (NPs), required for the fabrication of a glucose biosensor.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Target Organs

respiratory tract irritation

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Polymorphism of nickel sulfate hexahydrate.
Angel RJ and Finger LW.
Acta Crystallographica Section C, Crystal Structure Communications, 44(11), 1869-1873 (1988)
Amperometric glucose biosensor based on NiFe2O4 nanoparticles and chitosan.
Luo L, et al.
Sensors and Actuators B, Chemical, 145(1), 293-298 (2010)
Mechanism and kinetics of thermal decomposition of nickel (II) sulfate (VI) hexahydrate.
Tomaszewicz E and Kotfica M.
Journal of Thermal Analysis and Calorimetry, 77(1), 25-31 (2004)
Charlotte G Mortz et al.
Pediatric allergy and immunology : official publication of the European Society of Pediatric Allergy and Immunology, 24(1), 84-87 (2013-01-22)
We have previously reported patch test reactivity to nickel sulphate in a cohort of unselected infants tested repeatedly at 3-18 months of age. A reproducible positive reaction at 12 and 18 months was selected as a sign of nickel sensitivity provided a
Guangwei Si et al.
Lab on a chip, 12(7), 1389-1394 (2012-03-01)
We developed a multiple-channel microfluidic device for bacterial chemotaxis detection. Some characteristics such as easy operation, parallel sample adding design and fast result readout make this device convenient for most biology labs. The characteristic feature of the design is the

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