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33428

4,4′-MDI

analytical standard

Synonym(s):

4,4′-Methylenebis(phenyl isocyanate), 4,4′-Diphenylmethane diisocyanate, 4,4′-Methylenediphenyl diisocyanate, 4,4′-MDI, Bis(4-isocyanatophenyl)methane

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Size/SKUAvailabilityPrice
100 mg
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PLN 376.00
PLN 319.60

About This Item

Linear Formula:
CH2(C6H4NCO)2
CAS Number:
Molecular Weight:
250.25
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
202-966-0
Beilstein/REAXYS Number:
797662
MDL number:

PLN 319.60

List PricePLN 376.00Save 15%

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grade

analytical standard

Quality Segment

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

bp

200 °C/5 mmHg (lit.)

mp

42-45 °C (lit.)

density

1.18 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

storage temp.

−20°C

SMILES string

O=C=Nc1ccc(Cc2ccc(cc2)N=C=O)cc1

InChI

1S/C15H10N2O2/c18-10-16-14-5-1-12(2-6-14)9-13-3-7-15(8-4-13)17-11-19/h1-8H,9H2

InChI key

UPMLOUAZCHDJJD-UHFFFAOYSA-N

General description

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.
4,4′-MDI can be extensively used to make urethane elastomers and urethane coatings.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
4,4′-MDI may be used as an analytical standard for the determination of the analyte in wastewater and air samples,[1] and human biological samples by various chromatographic techniques.

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This Item
334903349335602
technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

environmental

application(s)

environmental

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

application(s)

environmental

format

neat

format

neat

format

neat

format

neat

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

grade

analytical standard

grade

analytical standard

grade

analytical standard

grade

analytical standard

storage temp.

−20°C

storage temp.

-

storage temp.

2-8°C

storage temp.

-


pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Carc. 2 - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Inhalation - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

411.8 °F - closed cup

flash_point_c

211 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

101-68-8

CAS No.


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Certificates of Analysis (COA)

Lot/Batch Number

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Questions

1–3 of 3 Questions  
  1. posso deixar o produto fora do freezer? ou sempre depois que eu terminar de utilizar tenho que colocar novamente no congelador? como faço para ele ficar liquído, apenas deixando fora do congelador ou tenho que aquece?

    1 answer
    1. The recommended storage temperature is -20°C; this product should be returned to the freezer after use to preserve quality. Prolonged exposure to higher temperatures can cause degradation. The melting point of this product is between 37°C and 45°C, so leaving it at room temperature will not liquefy it. To liquefy, use a controlled heat source such as a water bath set between 60°C and 80°C.

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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