Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

417459

Sigma-Aldrich

N-Methyl-1-(methylthio)-2-nitroethenamine

98%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
O2NCH=C(SCH3)NHCH3
CAS Number:
61832-41-5
Molecular Weight:
148.18
EC Number:
263-266-9
MDL number:
MFCD00040994
UNSPSC Code:
12352100
PubChem Substance ID:
24866151
NACRES:
NA.22

Assay

98%

form

solid

mp

112-118 °C (lit.)

functional group

amine
nitro
thioether

SMILES string

CN\C(SC)=C/[N+]([O-])=O

InChI

1S/C4H8N2O2S/c1-5-4(9-2)3-6(7)8/h3,5H,1-2H3/b4-3+

InChI key

YQFHPXZGXNYYLD-ONEGZZNKSA-N

Looking for similar products? Visit Product Comparison Guide

Application

(E) N-methyl-1-(methylthio)-2-nitroethenamine) (NMSM) may be used for the following syntheses:
  • pyrano[2,3-c]pyrazol-6-amines
  • 6-methoxy-N-methyl-3-nitro-4-nitromethyl-4H-chromen-2-amine

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
11830AS
03614MF

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Selvaraj Kanchithalaivan et al.
ACS combinatorial science, 15(12), 631-638 (2013-10-24)
An efficient one-pot four-component domino protocol for the combinatorial synthesis of novel 1,4-dihydropyrano[2,3-c]pyrazol-6-amines has been achieved. This transformation presumably occurs via cyclization-Knoevenagel condensation-Michael addition-tautomerism-intramolecular O-cyclization-elimination sequence of reactions. The significant features of this reaction include expedient one-pot process, short reaction
6-Methoxy-N-methyl-3-nitro-4-nitromethyl-4H-chromen-2-amine.
Muthukumaran J, et al.
Acta Crystallographica Section E, Structure Reports Online, 67(5), 1276-1277 (2011)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service