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40702

Sigma-Aldrich

5,7-Dimethyl-8-quinolinol

≥98.0% (GC)

Synonym(s):

5,7-Dimethyl-8-hydroxyquinoline

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About This Item

Empirical Formula (Hill Notation):
C11H11NO
CAS Number:
37873-29-3
Molecular Weight:
173.21
Beilstein:
1451007
MDL number:
MFCD00168976
UNSPSC Code:
12352100
PubChem Substance ID:
57650012

Assay

≥98.0% (GC)

mp

95-98 °C

SMILES string

Cc1cc(C)c2cccnc2c1O

InChI

1S/C11H11NO/c1-7-6-8(2)11(13)10-9(7)4-3-5-12-10/h3-6,13H,1-2H3

InChI key

UKWMNFHGYXRSFQ-UHFFFAOYSA-N

General description

5,7-Dimethyl-8-quinolinol (Me2-quoH) is a specific non-extracting reagent for lanthanide ions at pH below 11. It is useful for the extraction of Al3+ metal ions and the transition metal ions at ordinary pH conditions.

Application

5,7-Dimethyl-8-quinolinol has been used in the preparation of the following:
  • tetrakis(5,7-dimethylquinolin-8-olato-κ2N,O)zirconium(IV) dimethylformamide disolvate
  • tetrakis (5, 7-dimethylquinolin-8-olato-κ2N,O) hafnium (IV) dimethylformamide disolvate
  • [Ru(Me2-quo)(dcbpy)2]+Cl- (dcbpy = 2,2′-bipyridinyl-4,4′-dicarboxyl acid; Me2-quo = 5,7-dimethyl-8-hydroxyquinolinate)
  • bis(5,7-dimethyl-8-hydroxyquinolinato)platinum(II) complex

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Tetrakis (5, 7-dimethylquinolin-8-olato-κ2N,O) hafnium (IV) dimethylformamide disolvate.
Viljoen J, et al.
Acta Crystallographica Section E, Structure Reports Online, 67(10), 1428-1429 (2011)
Tetrakis (5, 7-dimethylquinolin-8-olato-κ2N,O) zirconium (IV) dimethylformamide disolvate.
Steyn M, et al.
Acta Crystallographica Section E, Structure Reports Online, 68(11), 1344-1345 (2012)
Bis (5,7-dimethyl-8-hydroxyquinolinato) platinum (II) Complex for Efficient Organic Heterojunction Solar Cells.
Low KH, et al.
Chemistry - An Asian Journal, 6(12), 3223-3229 (2011)
5, 7-Dimethyl-8-quinolinol as a Specific Non-extracting Reagent for Lanthanide Ions at Usual pH Region.
Takayanagi T, et al.
Chemistry Letters (Jpn), 4, 687-690 (1994)
Ruthenium oxyquinolate complexes for dye-sensitized solar cells.
Dragonetti C, et al.
Inorgorganica Chimica Acta, 405, 98-104 (2013)
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