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163015

Sigma-Aldrich

Thallium(III) nitrate trihydrate

Synonym(s):

TTN, Thallium trinitrate

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About This Item

Linear Formula:
Tl(NO3)3 · 3H2O
CAS Number:
13453-38-8
Molecular Weight:
444.44
EC Number:
237-325-4
MDL number:
MFCD00149874
UNSPSC Code:
12161600
PubChem Substance ID:
24850018
NACRES:
NA.22

Quality Level

100

reaction suitability

core: thallium
reagent type: catalyst

mp

102-105 °C (lit.)

SMILES string

O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3

InChI key

ZCPIKMRXMBJLCP-UHFFFAOYSA-N

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Application

Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.

Signal Word

Danger

Hazard Statements

H300 + H330,H373,H411

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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