687510
Chloro[2-dicyclohexyl(2′,4′,6′-trisopropylbiphenyl)phosphine]gold(I)
Synonym(s):
2-Dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl gold(I) chloride, XPhos AuCl
About This Item
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form
solid
Quality Level
reaction suitability
core: gold
reagent type: catalyst
mp
243-250 °C
SMILES string
Cl[Au].CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI
1S/C33H49P.Au.ClH/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;;1H/q;+1;/p-1
InChI key
AFVLNRJUCUDBHP-UHFFFAOYSA-M
Application
- Michael addition and intramolecular hydroalkylation reactions
- Cascade cyclization of diynes
- Hydroarylation of allenes via a highly regioselective carbon-carbon bond formation producing six-membered rings
- Alkyne cyclizations in a Holey catalytic environment
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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