388076

tert-Butyl peracetate solution

50 wt. % in odorless mineral spirits

• Synonym(s): tert -Butyl peracetate, tert -Butyl peroxyacetate
• Linear Formula: CH₃CO₃C(CH₃)₃
• CAS Number: 107-71-1
• Molecular Weight: 132.16
• MDL number: MFCD00048240
• UNSPSC Code: 12162002
• PubChem Substance ID: 24864203
• NACRES: NA.23

Properties

• form: liquid
• Quality Level: 100
• t1/2: 10 hr(101 °C, 0.2 M in benzene)
• concentration: 50 wt. % in odorless mineral spirits
• refractive index: n20/D 1.412
• density: 0.828 g/mL at 25 °C
• SMILES string: CC(=O)OOC(C)(C)C
• InChI: 1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3
• InChI key: SWAXTRYEYUTSAP-UHFFFAOYSA-N

Description

Application

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.

Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF₃)ppy}₂(dtbpy)]PF₆ (Aldrich L511765) for late-stage functionalization of biologically active heterocycles.

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Safety Information

• Flash Point(F): 98.6 °F - closed cup
• Flash Point(C): 37 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves