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25102

Sigma-Aldrich

9-(Chloromethyl)anthracene

BioReagent, suitable for fluorescence, ≥97.0% (AT)

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About This Item

Empirical Formula (Hill Notation):
C15H11Cl
CAS Number:
24463-19-2
Molecular Weight:
226.70
Beilstein:
1873394
EC Number:
246-274-7
MDL number:
MFCD00001263
UNSPSC Code:
12352200
PubChem Substance ID:
329752775
Pricing and availability is not currently available.

product line

BioReagent

Assay

≥97.0% (AT)

mp

138-140 °C (lit.)

fluorescence

λex 356 nm; λem 412 nm (after derivatisation with sodium acetate)

suitability

suitable for fluorescence

SMILES string

ClCc1c2ccccc2cc3ccccc13

InChI

1S/C15H11Cl/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9H,10H2

InChI key

PCVRSXXPGXRVEZ-UHFFFAOYSA-N

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Analysis Note

In addition to the emission maximum at 412 nm, there are lower maxima at 434, 395 and 459 nm.

Other Notes

Blocking group reagent for carboxylic acids, phenols, thiophenols and mercaptans[1]; Derivatizing agent for carboxylic acids giving esters with enhanced UV and fluorescence detection in HPLC[2]

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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W.D. Korte
Journal of Chromatography A, 243, 153-153 (1982)
Jason P Schrum et al.
Journal of the American Chemical Society, 131(40), 14560-14570 (2009-09-18)
The development of a sequence-general nucleic acid copying system is an essential step in the assembly of a synthetic protocell, an autonomously replicating spatially localized chemical system capable of spontaneous Darwinian evolution. Previously described nonenzymatic template-copying experiments have validated the
Dorothea F K Rawn et al.
Journal of chromatography. A, 1080(2), 148-156 (2005-07-13)
A rapid and simple method for confirmation of the diarrhetic shellfish poisons (DSP): okadaic acid (OA), dinophysistoxin-1 (DTX-1) and dinophysistoxin-2 (DTX-2) using fluorescence detection following derivatization with 9-chloromethylanthracene, has been established as an alternate to LC/MS. Exposure of the anthrylmethyl
J F Lawrence et al.
Journal of chromatography. A, 721(2), 359-364 (1996-01-19)
The reagent 9-chloromethylanthracene was evaluated for derivatization of the diarrhetic shellfish poisons, okadaic acid and dinophysistoxin-1 (DTX-1), to form fluorescent products separable by liquid chromatography. The toxins were reacted with the reagent in acetonitrile in the presence of tetramethylammonium hydroxide
Ying Zhang et al.
Colloids and surfaces. B, Biointerfaces, 44(2-3), 104-109 (2005-07-26)
Polymeric micelles based on amphiphilic diblock copolymers methoxy poly(ethylene glycol)-polylactide with various hydrophobic lengths were designed as carriers of poorly water-soluble anticancer drug methotrexate (MTX). Relationship between physicochemical characteristics of micelles and release behavior was explored. The critical micelle concentration
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