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737321

Sigma-Aldrich

Triphenylbismuth

98% (99.9% trace metals basis)

Synonym(s):

TPB

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About This Item

Linear Formula:
Bi(C6H5)3
CAS Number:
Molecular Weight:
440.29
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
Pricing and availability is not currently available.

Assay

98% (99.9% trace metals basis)

form

powder or crystals

reaction suitability

core: bismuth

availability

available only in USA

mp

76-81 °C

SMILES string

c1ccc(cc1)[Bi](c2ccccc2)c3ccccc3

InChI

1S/3C6H5.Bi/c3*1-2-4-6-5-3-1;/h3*1-5H;

InChI key

ZHXAZZQXWJJBHA-UHFFFAOYSA-N

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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H R Rawls et al.
Journal of biomedical materials research, 31(3), 339-343 (1996-07-01)
Previously we demonstrated the feasibility of using up to 24% triphenylbismuth (TPB) as a radiopaque, monomer-miscible additive for dental acrylic resins. In this study we examined the influence of TPB on thermomechanical properties of a representative polymethylmethacrylate (PMMA) ambient-cured resin
S Deb et al.
Biomaterials, 23(16), 3387-3393 (2002-07-09)
In a joint replacement surgery it is vital for bone cement to be radiologically detectable. Consequently, heavy metal salts of barium and zirconia are incorporated as a contrast medium for this purpose. The addition of such particulate additives, however, can
Raphael J F Berger et al.
Physical chemistry chemical physics : PCCP, 14(44), 15520-15524 (2012-10-18)
Relativistic effects in triphenylbismuth have been investigated using a combined experimental and theoretical approach. The influence of these effects on the molecular structure (determined by gas electron diffraction) has been evaluated by means of quantum chemical calculations which consider scalar-relativistic
Stejskal, J.; Leitner, J.J.; Sedmidubsky, D. et al
Journal of Crystal Growth, 210, 587-587 (2000)
O Anjaneyulu et al.
Dalton transactions (Cambridge, England : 2003), 41(3), 1004-1012 (2011-11-23)
The reaction of triphenylbismuth [BiPh(3)] with several heterocyclic carboxylic acids was explored. Seven crystalline compounds, [PhBi(2-O(2)C-3-(OH)C(5)H(3)N)(2)(2-O(2)C-3-(OH)C(5)H(3)NH)] (5), [(Bi(2-O(2)C-3-(OH)C(5)H(3)N)(4))(C(5)H(5)NH)(C(5)H(5)N)] (7), [PhBi(2-O(2)C-C(4)H(3)N(2))(2)(2-O(2)C-C(4)H(4)N(2))·H(2)O] (8), [PhBi(2-O(2)C-C(9)H(6)N)(2)·H(2)O] (9), [Ph(2)Bi(O(2)C-C(4)H(3)O)] (10), [Ph(2)Bi(O(2)C-C(4)H(3)S)] (11) and [PhBi(O(2)C-C(4)H(3)S)(2)](2) (12), were prepared by simple reactions using BiPh(3) and the corresponding

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