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S-(α-Fluorobenzyl)-S-phenyl-N-(p-tolylsulfonyl)sulfoximine

Name: S-(α-Fluorobenzyl)-S-phenyl-N-(p-tolylsulfonyl)sulfoximine
Brand: ALDRICH

97%

Synonym(s):

N-[(fluorophenylmethyl)oxidophenyl-λ₄-sulfanylidene]-4-methyl-benzenesulfonamide

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About This Item

Empirical Formula (Hill Notation):

C₂₀H₁₈FNO₃S₂

CAS Number:

1260143-68-7

Molecular Weight:

403.49

MDL number:

MFCD18910698

UNSPSC Code:

12352101

PubChem Substance ID:

329764564

NACRES:

NA.22

Assay

97%

form

solid

mp

148-154 °C

SMILES string

Cc1ccc(cc1)S(=O)(=O)N=S(=O)(C(F)c2ccccc2)c3ccccc3

InChI

1S/C20H18FNO3S2/c1-16-12-14-19(15-13-16)27(24,25)22-26(23,18-10-6-3-7-11-18)20(21)17-8-4-2-5-9-17/h2-15,20H,1H3

InChI key

ZAGQEXRRSCLLFW-UHFFFAOYSA-N

Application

S-(α-Fluorobenzyl)-S-phenyl-N-(p-tolylsulfonyl)sulfoximine can be used as a reagent for the synthesis of monofluorinated epoxides byO-cyclization reaction with ketones in the presence of a strong base.

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335,H413

Precautionary Statements

P261 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from a-Fluorosulfoximines

Zhang, W.; Hu, J.

Advanced Synthesis & Catalysis, 352, 2799-2804 (2010)

Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from α-Fluorosulfoximines

Zhang W and Hu J

advanced synthesis and catalysis, 352(16), 2799-2804 (2010)