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Sigma-Aldrich

(3-Mercaptopropyl)triethoxysilane

≥80% (GC), technical

Synonym(s):

3-Triethoxysilyl-1-propanethiol

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About This Item

Linear Formula:
HS(CH2)3Si(OCH2CH3)3
CAS Number:
14814-09-6
Molecular Weight:
238.42
Beilstein:
2039575
EC Number:
238-883-1
MDL number:
MFCD00053924
UNSPSC Code:
12352103
PubChem Substance ID:
57651963
NACRES:
NA.22
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grade

technical

Assay

≥80% (GC)

density

0.987 g/mL at 20 °C (lit.)

functional group

thiol

storage temp.

2-8°C

SMILES string

CCO[Si](CCCS)(OCC)OCC

InChI

1S/C9H22O3SSi/c1-4-10-14(11-5-2,12-6-3)9-7-8-13/h13H,4-9H2,1-3H3

InChI key

DCQBZYNUSLHVJC-UHFFFAOYSA-N

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General description

3-mercaptopropyl trimethoxysilane (MPTMS) is commonly used in surface modification of silica nanoparticles by creating thiol group on the surface.[1]

Application

(3-Mercaptopropyl)triethoxysilane (MPTS) can be used as a reagent to prepare thiol functionalized materials. Silica, SBA-15, alumina, starch, and graphene can be functionalized with MPTS and used in various applications.[2][3][4][5]
MPTS functionalized SBA-15 probe is used to determine dissolved mercury in solution.[2]

Pictograms

Environment
GHS09

Hazard Statements

H411

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Chronic 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

190.4 °F - closed cup

Flash Point(C)

88 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM2726
BCCF2080
BCBZ5121
BCBW3515
BCBS2898V

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Fabrication of hybrids based on graphene and metal nanoparticles by in situ and self-assembled methods
He F-A, et al.
Nanoscale, 3(3), 1182-1188 (2011)
Electroless copper deposition on (3-mercaptopropyl) triethoxysilane-coated silica and alumina nanoparticles
Mondin G, et al.
Electrochimica Acta, 114, 521-526 (2013)
Surface modification of nanosilica with 3-mercaptopropyl trimethoxysilane: Experimental and theoretical study on the surface interaction
Wu J, et al.
Chemical Physics Letters, 591, 227-232 (2014)
Zidan Wang et al.
Nanoscale, 10(11), 5335-5341 (2018-03-07)
A novel zwitterionic hydrophilic magnetic mesoporous silica was prepared for endogenous glycopeptide enrichment prior to MS analysis. For the first time, the material was successfully applied in capturing endogenous glycopeptides from human saliva, indicating great potential of this strategy for
Hongqiang Zhai et al.
International journal of molecular sciences, 19(12) (2018-11-30)
Dimercaptosuccinic acid (DMSA) is an oral heavy metal chelator. Although DMSA is the most acceptable chelator in the urinary excretion of toxic elements from children and adults, its defects in plasma binding and the membrane permeability limit its interaction with
View All Related Papers

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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