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447242

Sigma-Aldrich

1,2-Bis(trimethoxysilyl)ethane

96%

Synonym(s):

1,2-Bis(trimethoxysilyl)ethane, 1,2-Ethylenebis(trimethoxysilane)

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About This Item

Linear Formula:
[-CH2Si(OCH3)3]2
CAS Number:
Molecular Weight:
270.43
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Assay

96%

form

liquid

refractive index

n20/D 1.409 (lit.)

bp

103-104 °C/5 mmHg (lit.)

density

1.073 g/mL at 25 °C (lit.)

SMILES string

CO[Si](CC[Si](OC)(OC)OC)(OC)OC

InChI

1S/C8H22O6Si2/c1-9-15(10-2,11-3)7-8-16(12-4,13-5)14-6/h7-8H2,1-6H3

InChI key

JCGDCINCKDQXDX-UHFFFAOYSA-N

General description

1,2-Bis(trimethoxysilyl)ethane (BTME) is a bridged alkoxysilane that can be used as an organosilica based precursor that forms mesoporous materials. It can be prepared by hydrolyzing the alkoxy groups with Si-OH to form Si-O-Si structure.

Application

BTME can be used to synthesize a shell based nanocomposite for potential application in drug delivery and encapsulation. It can also form magnetic hollow spheres which find usage in magnetic resonance imaging (MRI).
Functionalized mesoporous silica was synthesized from 1,2-bis(trimethoxysilyl)ethane.{27}

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Acute Tox. 1 Inhalation

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

228.2 °F - closed cup

Flash Point(C)

109 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Organic- inorganic hybrid hollow nanospheres with microwindows on the shell
Liu J, et al.
Chemistry of Materials, 163(11), 178-185 (2008)
Multiscale templating of siloxane gels via polymerization-induced phase separation
Nakanishi K, et al.
Chemistry of Materials, 20(3), 1108-1115 (2007)
Very stable phosphiranes
Liedtke J, et al.
Angewandte Chemie (International ed. in English), 38(11), 1623-1626 (1999)
One-pot synthesis of hybrid mesoporous xerogels starting with linear polymethylhydrosiloxane and bridged bis-(trimethoxysilyl) ethane
Zhai S, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 163(11), 178-185 (2012)
Magnetic hollow spheres of periodic mesoporous organosilica and Fe3O4 nanocrystals: fabrication and structure control
Zhang L, et al.
Advanced Materials, 20(4), 805-809 (2008)

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