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440248

Sigma-Aldrich

Dichloromethylsilane

≥97%

Synonym(s):

Methyldichlorosilane

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About This Item

Linear Formula:
CH3SiHCl2
CAS Number:
Molecular Weight:
115.03
Beilstein:
1071194
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

vapor density

4 (vs air)

Quality Level

vapor pressure

6.79 psi ( 20 °C)

Assay

≥97%

form

liquid

autoignition temp.

471 °F

expl. lim.

>55 %

refractive index

n20/D 1.398 (lit.)

bp

41 °C (lit.)

mp

−93 °C (lit.)

density

1.105 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[SiH](Cl)Cl

InChI

1S/CH4Cl2Si/c1-4(2)3/h4H,1H3

InChI key

NWKBSEBOBPHMKL-UHFFFAOYSA-N

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General description

Dimethyldichlorosilane(DMDCS) is a tetrahedral organosilicon compound. It is used as a silane coupling agent to synthesis the hydrophilic and hydrophobic silica nanoparticles. It is also used in the synthesis of polysilanes, which are precursors to silicon carbide.

Application


  • A General and Selective Synthesis of Methylmonochlorosilanes from Di-, Tri-, and Tetrachlorosilanes - Discusses a method for synthesizing Methylmonochlorosilanes, showing potential for varied applications in chemical synthesis (Y Naganawa et al., 2020).

  • Polymerization of methylsilylenes into polymethylsilanes or polycarbosilanes after dechlorination of dichloromethylsilanes. - Investigates the polymerization of methylsilylenes, offering insights into the production of polymethylsilanes or polycarbosilanes from Dichloromethylsilanes (Y Tian et al., 2016).

  • Synthesis of low viscosity of polymethylhydrosiloxane using monomer of dichloromethylsilane - Focuses on producing low-viscosity polymethylhydrosiloxane through hydrolysis-condensation of Dichloromethylsilane, significant for various industrial applications (VF Arini et al., 2022).


Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Water-react 3

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

-18.4 °F

Flash Point(C)

-28 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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K Kim et al.
Journal of biomedical materials research, 52(4), 836-840 (2000-10-18)
In order to develop a versatile model for blood-compatible materials, we studied morphology and platelet adhesion of a dipalmitoyl-phosphatidylcholine (DPPC)/dipalmitoyl-phosphatidylethanolamine-polyethylene glycol (PEG lipid) mixed monolayer. This monolayer, which mimics the cell membrane structure, consists of two heterogeneous layers, that is
Jaleh Varshosaz et al.
Drug delivery, 11(1), 53-58 (2004-06-01)
Hydroxyethylmethacrylate/methacrylic acid copolymer cross-linked with ethylenglycol dimethacrylate was prepared by a bulk free radical polymerization method. The permeability studies of this pH-sensitive hydrogel to drugs with different water solubilities showed a water-content dependent diffusion or pore mechanism for ephedrine HCl
Jing Li et al.
Journal of cellular physiology, 235(9), 6139-6153 (2020-02-06)
Atherosclerosis is one of the leading causes of morbidity and mortality, mainly due to the immune response triggered by the recruitment of monocytes/macrophages in the artery wall. Accumulating evidence have shown that matrix stiffness and oxidized low-density lipoproteins (ox-LDL) play
Multihydroxy-functional polysilanes via an acetal protecting group strategy
Reuss VS and Frey H
Macromolecules, 43(20) (2010)
Dichlorodimethylsilane mediated one-step synthesis of hydrophilic and hydrophobic silica nanoparticles
Ebrahimi F, et al.
Advanced Powder Technology, 28(3), 932-937 (2017)

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