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391123

Sigma-Aldrich

Tris(dibenzoylmethanato)iron

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About This Item

Empirical Formula (Hill Notation):
C45H36FeO6
CAS Number:
Molecular Weight:
728.61
MDL number:
UNSPSC Code:
12352103

SMILES string

O=C(\C=C(\O[Fe](O\C(=C\C(=O)c1ccccc1)c2ccccc2)O\C(=C\C(=O)c3ccccc3)c4ccccc4)c5ccccc5)c6ccccc6

Application

Air-stable, non-hygroscopic, THF-soluble catalyst for the coupling of alkenyl halides with Grignard reagents, and for the samarium(II) iodide promoted intramolecular Barbier-type reaction for the synthesis of bicyclo[m.n.l]alkan-1-ols.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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The Journal of Organic Chemistry, 40, 599-599 (1975)
The Journal of Organic Chemistry, 56, 4112-4112 (1991)

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