Skip to Content
Merck
All Photos(2)

Key Documents

View All Documentation

263354

Sigma-Aldrich

2-Bromo-5-methylpyridine

98%

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C6H6BrN
CAS Number:
3510-66-5
Molecular Weight:
172.02
MDL number:
MFCD00209553
UNSPSC Code:
12352100
PubChem Substance ID:
24855964
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

100

Assay

98%

form

solid

bp

95-96 °C/12.5 mmHg (lit.)

mp

41-43 °C (lit.)

functional group

bromo

SMILES string

Cc1ccc(Br)nc1

InChI

1S/C6H6BrN/c1-5-2-3-6(7)8-4-5/h2-4H,1H3

InChI key

YWNJQQNBJQUKME-UHFFFAOYSA-N

Application

2-Bromo-5-methylpyridine has been used as starting reagent for the synthesis of:
  • 5,5′-dimethyl-2,2′-bipyridine[1]
  • 5-methyl-2,2′:6′,2″-terpyridine[2]
  • 5-bromo-5″-methyl-2,2′:6′,2″-terpyridine[3]

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

217.4 °F - closed cup

Flash Point(C)

103 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCL3526
MKBS6823V
MKBR8815V
MKBQ0907V
03696AKV

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

High yield synthesis of 5, 5'-dimethyl-2, 2'-bipyridine and 5, 5 ?-dimethyl-2, 2': 6', 2 ?-terpyridine and some bisfunctionalization reactions using N-bromosuccinimide.
Schubert US, et al.
Synthesis, 1999(5), 779-782 (1999)
Ben Yiu-Wing Wong et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 22(42), 15095-15106 (2016-09-07)
A series of air-stable spiro-fused ladder-type boron(III) compounds has been designed, synthesized, and the electrochemistry and photophysical behavior have been characterized. By simply varying the substituents on the pyridine ring and extending the π-conjugation of the spiro framework, the emission
Synthesis of two covalently linked bis (2, 2': 6', 2''-terpyridine)(terpy) chelating ligands with different length spacers, comparison of the crystal structures of their mononuclear nickel (II) complexes, and kinetic and mechanistic studies of the reaction of one ligand with [Fe (terpy) 2] 2+.
Priimov GU, et al.
J. Chem. Soc., Dalton Trans., 4, 445-449 (2000)
Synthesis of a novel ditopic ligand incorporating directly bonded 1, 10-phenanthroline and 2, 2': 6', 2 ?-terpyridine units.
Gavi?a P and Tatay S.
Tetrahedron Letters, 47(20), 3471-3473 (2006)

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service