Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
189901
Methylmagnesium chloride solution
3.0 M in THF
Synonym(s):
Chloromethylmagnesium, Methyl magnesium chloride, Methylmagnesiumchloride
About This Item
Recommended Products
autoignition temp.
609 °F
Quality Level
reaction suitability
reaction type: Grignard Reaction
concentration
3.0 M in THF
density
1.013 g/mL at 25 °C
SMILES string
C[Mg]Cl
InChI
1S/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1
InChI key
RQNMYNYHBQQZSP-UHFFFAOYSA-M
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Application
Packaging
Legal Information
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
1.0 °F - closed cup
Flash Point(C)
-17.2 °C - closed cup
Personal Protective Equipment
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How is shipping temperature determined? And how is it related to the product storage temperature?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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In one litere of tetra hydra furan THF, how much of methyl megnesium chloride should be requried?
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The molar mass of methylmagnesium chloride is 74.79 g/mol. This product is a 3.0 M methylmagnesium chloride solution in THF. This corresponds to 224.37 grams of methylmagnesium chloride per liter of THF to achieve this concentration.
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Can Product 189901, Methylmagnesium chloride solution, be used if a precipitate is present?
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If a precipitate is present, the product can be heated and stirred until the precipitate is dissolved.
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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Is the BHT inhibitor present in Product 189901, Methylmagnesium chloride solution?
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Yes, BHT is present in the THF. This information can be found on the MSDS, which is available from our website.
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