176494

Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]

• Synonym(s): Eu(facam)₃, Eu(tfc)₃, Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate], Tris(3-trifluoroacetyl-d-camphorato)europium(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)
• Empirical Formula (Hill Notation): C₃₆H₄₂EuF₉O₆
• CAS Number: 34830-11-0
• Molecular Weight: 893.66
• EC Number: 252-232-9
• MDL number: MFCD00074803
• UNSPSC Code: 12352115
• PubChem Substance ID: 24850581
• NACRES: NA.22

Properties

• optical activity: [α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)
• technique(s): NMR: suitable
• SMILES string: CC1(C)C2CCC1(C)C(=O)\C2=C(/O[Eu](O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F
• InChI: 1S/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;
• InChI key: BWIHMSGCCRUUCZ-NCJHBDPTSA-K

Description

Application

Reactant involved in:

• The synthesis of europium acetylcamphorate phosphine oxide complexes
• Reactions with 1,10-N,N′-phenanthroline dioxide derivatives

Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves