63102
Magnesium perchlorate
puriss., free-flowing powder, ≥99.0% (calc. based on dry substance, KT)
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About This Item
Linear Formula:
Mg(ClO4)2
CAS Number:
Molecular Weight:
223.21
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
Assay:
≥99.0% (calc. based on dry substance, KT)
form:
free flowing powder
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grade
puriss.
Quality Level
Assay
≥99.0% (calc. based on dry substance, KT)
form
free flowing powder
quality
free-flowing powder
impurities
≤8% water
storage temp.
room temp
SMILES string
[Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
InChI
1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
InChI key
MPCRDALPQLDDFX-UHFFFAOYSA-L
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General description
Magnesium perchlorate (Mg(ClO4)2) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.
Application
Magnesium perchlorate (Mg(ClO4)2) may be employed as a catalyst in the following studies:
- Preparation of a-aminophosphonates.
- Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one.
- Preparation of imines and phenylhydrazones.
- Protection of alcohols in the form of t-butyl ethers.
filler for drying tubes (especially for elemental analysis)
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Magnesium perchlorate as an efficient catalyst for the synthesis of imines and phenylhydrazones.
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Tetrahedron Letters, 45(41), 7641-7644 (2004)
Eagleson M.
Concise Encyclopedia Chemistry, 343-343 (1994)
The first enantioselective synthesis of both Diels-Alder enantiomers with the same bis (oxazoline)-magnesium perchlorate chiral catalyst.
Desimoni G, et al.
Tetrahedron Letters, 37(17), 3027-3030 (1996)
F Javier Céspedes-Guirao et al.
The Journal of organic chemistry, 74(16), 5871-5880 (2009-07-29)
Zinc phthalocyanine-perylenebisimide pentameric arrays, ZnPc(PDI)(4) 1 and 2, have been synthesized. ZnPc(PDI)(4) 1 has no substituents in the PDI bay positions, while ZnPc(PDI)(4) 2 presents four phenoxy groups in the bay positions of each perylene. In both cases, the PDI
J D Anastassopoulou
Magnesium research, 3(1), 19-21 (1990-03-01)
The mechanism of the gamma-radiolysis of the nucleotide guanosine-5'-monophosphate (5'-GMP) in the presence of Mg++ ions and cis-platinum was investigated. From high performance liquid chromatography and spectroscopy studies it was found that the OH radicals, produced in irradiated aqueous solutions
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