Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

923478

Sigma-Aldrich

CyMPhos

Synonym(s):

1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C42H60FeP2
Molecular Weight:
682.72
NACRES:
NA.21

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand

Quality Level

100

functional group

phosphine

SMILES string

c1(P(C2CCCCC2)C3CCCCC3)cccc1.c4(P([C@@]56C[C@@H](C[C@H]7C6)C[C@@H](C7)C5)[C@@]89C[C@@H](C[C@H]%10C9)C[C@@H](C%10)C8)cccc4.[Fe]

Related Categories

Application

CyMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing CyMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2?Csp3 Couplings
Guolin Xu, Peng Gao, and Thomas J. Colacot
ACS Catalysis, 12, 5123?5135-5123?5135 (2022)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service