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688509

Sigma-Aldrich

Silicon tetrachloride

packaged for use in deposition systems

Synonym(s):

STC, Tetrachlorosilane

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About This Item

Linear Formula:
SiCl4
CAS Number:
10026-04-7
Molecular Weight:
169.90
MDL number:
MFCD00011229
UNSPSC Code:
12352103
PubChem Substance ID:
329761169
NACRES:
NA.23

vapor density

5.86 (vs air)

Quality Level

100

vapor pressure

420 mmHg ( 37.7 °C)

Assay

99.998% trace metals basis

form

liquid

reaction suitability

core: silicon

bp

57.6 °C (lit.)

mp

−70 °C (lit.)

density

1.483 g/mL at 25 °C (lit.)

SMILES string

Cl[Si](Cl)(Cl)Cl

InChI

1S/Cl4Si/c1-5(2,3)4

InChI key

FDNAPBUWERUEDA-UHFFFAOYSA-N

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General description

Atomic number of base material: 14 Silicon

Application

Precursors Packaged for Depositions Systems

Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

Signal Word

Danger

Hazard Statements

H301 + H331,H314,H335

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH071

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ2687
SHBM7565
SHBK6266
SHBF7138V
06618LH

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D Khushalani et al.
Journal of nanoscience and nanotechnology, 1(2), 129-132 (2003-08-14)
Mesostructured silica-nanoparticle monolithic composites have been synthesized by dispersing prefabricated nanoparticles of gold or zeolite (silicalite) in ethanolic reaction mixtures containing SiCl4 and a Pluronic triblock copolymer template. Whereas silicalite nanoparticles were used directly, surface functionalization of the gold nanoparticles
Pulmonary interstitial emphysema: CT findings.
A C Kemper et al.
AJR. American journal of roentgenology, 172(6), 1642-1642 (1999-06-01)
K M Sivanandaiah et al.
International journal of peptide and protein research, 45(4), 377-379 (1995-04-01)
Deprotection of the tert-butoxycarbonyl group during solid-phase synthesis of peptides can be conveniently and efficiently carried out using a neutral reagent, silicon tetrachloride/sodium iodide (iodotrichlorosilane). This simple and rapid method has been advantageously employed during the solid-phase synthesis of the
Claudio Curti et al.
Organic letters, 13(17), 4738-4741 (2011-08-13)
Virtually perfect transmittal of the enolate reactivity up to five conjugated double bonds from the origin allows a series of furan-based silyloxypolyenes to add to aldehyde carbonyls at the most distant point of the molecule. Denmark's axially chiral bisphosphoramide/SiCl(4) combination
T Kapias et al.
Journal of hazardous materials, 81(3), 209-222 (2001-02-13)
Silicon tetrachloride is a toxic, corrosive water reactive substance that is used widely in the process industries. On spillage from containment it creates liquid pools that can either boil or evaporate. The main feature of the pool behaviour is the
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