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Key Documents

200891

Sigma-Aldrich

Vanadium(V) oxychloride

99%

Synonym(s):

Trichlorooxovanadium oxide, Vanadium(V) oxytrichloride, Vanadyl trichloride

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About This Item

Linear Formula:
VOCl3
CAS Number:
Molecular Weight:
173.30
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

vapor pressure

13.8 mmHg ( 20 °C)

Quality Level

Assay

99%

form

liquid

reaction suitability

reagent type: catalyst
core: vanadium

bp

126-127 °C (lit.)

mp

−77 °C (lit.)

density

1.84 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

Cl[V](Cl)(Cl)=O

InChI

1S/3ClH.O.V/h3*1H;;/q;;;;+3/p-3

InChI key

JBIQAPKSNFTACH-UHFFFAOYSA-K

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Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Masayuki Kirihara et al.
Chemical & pharmaceutical bulletin, 52(5), 625-627 (2004-05-11)
Thiols were converted into disulfide by the aerobic oxidation catalyzed by trichlorooxyvanadium in the presence of molecular sieves 3A.
[Hygienic characteristics of the working conditions in the manufacture of vanadium hydroxychloride].
B G Feĭgin et al.
Gigiena truda i professional'nye zabolevaniia, (1)(1), 51-52 (1985-01-01)
M D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56(14), 2693-2698 (2001-01-06)
A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI

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