239305

Sodium hypochlorite solution

reagent grade, available chlorine 4.00-4.99 %

• Fórmula lineal: NaClO
• Número de CAS: 7681-52-9
• Peso molecular: 74.44
• Número CE: 231-668-3
• Número MDL: MFCD00011120
• Código UNSPSC: 12352300
• ID de la sustancia en PubChem: 329752526
• NACRES: NA.21
• grado: reagent grade
• Formulario: liquid

Propiedades

• grado: reagent grade
• Nivel de calidad: 100
• Agency: suitable for SM 4500 - NH3
• presión de vapor: 17.5 mmHg ( 20 °C)
• Formulario: liquid
• composición: available chlorine, 4.00-4.99%
• idoneidad de la reacción: reagent type: oxidant
• concentración: 4.00-4.99% (chlorine by Na₂S₂O₃, titration)
• densidad: 1.097 g/mL at 25 °C
• temp. de almacenamiento: 2-8°C
• cadena SMILES: [Na+].[O-]Cl
• InChI: 1S/ClO.Na/c1-2;/q-1;+1
• Clave InChI: SUKJFIGYRHOWBL-UHFFFAOYSA-N

Descripción

Descripción general

Sodium hypochlorite (NaOCl) is a commonly used reagent in organic synthesis for many oxidation and chlorination reactions.

Aplicación

Sodium hypochlorite solution can be used as an oxidizing agent for the oxidation of:      

• Primary alcohols to aldehydes or carboxylic acids and secondary alcohols to ketones.     
• Aryl aldehydes to the corresponding acids in the presence of a phase-transfer catalyst.      
• Ethers to esters by careful pH control (pH range of 8–9.5),

It can also be used as a reagent in the:      

• Epoxidation of enones and polycyclic arenes.      
• Oxidative degradation reaction      
• N-Chlorination of primary and secondary amines
• Enantioselective epoxidation of α, β-unsaturated ketones      
• Asymmetric dihydroxylation of olefins in the presence of an osmium catalyst      
• Chlorination of allylic carbons in the presence of CeCl₃

Características y beneficios

• Readily available reagent      
• Easily handled oxidizing agent      
• No phase-transfer catalyst is necessary for the oxidation of substrates in the pH range 10–11     
• Simplified waste disposal and lower toxicity

Cláusula de descargo de responsabilidad

“The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others.”

Información de seguridad

• Pictogramas: GHS05,GHS09
• Palabra de señalización: Danger
• Frases de peligro: H315,H318,H410
• Consejos de prudencia: P264 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313
• Clasificaciones de peligro: Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2
• Código de clase de almacenamiento: 12 - Non Combustible Liquids
• Clase de riesgo para el agua (WGK): WGK 2
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable