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86485

Sigma-Aldrich

Terpinolene

technical, ≥85% (GC)

Sinónimos:

4-Isopropylidene-1-methylcyclohexene, p-Menth-1,4(8)-diene, p-Meth-1-en-8-yl-formate

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About This Item

Fórmula empírica (notación de Hill):
C10H16
Número de CAS:
586-62-9
Peso molecular:
136.23
Beilstein/REAXYS Number:
1851203
EC Number:
209-578-0
MDL number:
MFCD00049191
UNSPSC Code:
12352100
PubChem Substance ID:
329769467
NACRES:
NA.22

vapor density

~4.7 (vs air)

Quality Level

100

vapor pressure

~0.5 mmHg ( 20 °C)

grade

technical

assay

≥85% (GC)

form

liquid

refractive index

n20/D 1.489 (lit.)
n20/D 1.491

bp

184-185 °C (lit.)

density

0.861 g/mL at 25 °C (lit.)

SMILES string

C\C(C)=C1/CCC(C)=CC1

InChI

1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4H,5-7H2,1-3H3

InChI key

MOYAFQVGZZPNRA-UHFFFAOYSA-N

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General description

Terpinolene is a biogenically emitted monoterpene. Kinetics of gas phase reaction of OH and NO3 radicals with terpinolene has been investigated. Biotransformation of terpinolene byAspergillus niger and several related species has been reported. Epoxidation of terpinolene in anhydrous conditions using alumina as a heterogeneous catalyst and hydrogen peroxide as the oxidant agent has been studied. It is an major component of essential oil extracted from the aerial parts of Clausena indica.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 3 - Asp. Tox. 1 - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

141.8 °F - Seta closed cup

flash_point_c

61 °C - Seta closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
BCCG0698
BCCD7588
BCCD7586
BCCD2082
BCCD2073

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Kinetics of the gas-phase reactions of hydroxyl and nitrogen oxide (NO3) radicals with 2-carene, 1, 8-cineole, p-cymene, and terpinolene.
Corchnoy SB and Atkinson R.
Environmental Science & Technology Letters, 24(10), 1497-1502 (1990)
Tran Huy Thaia et al.
Natural product communications, 9(10), 1531-1534 (2014-12-20)
The chemical composition of Vietnamese oil samples of the aerial parts of Clausena indica (Dalz.) Oliver and C. anisum-olens (Blanco) Merryll have been investigated using a combination of chromatographic and spectroscopic techniques. C. indica essential oil contained mainly terpinolene (53.9
Alumina as heterogeneous catalyst for the regioselective epoxidation of terpenic diolefins with hydrogen peroxide.
Uguina MA, et al.
J. Mol. Catal. A: Chem., 256(1), 208-215 (2006)
Biotransformation of monoterpenoids,(-)-and menthols, terpinolene and carvotanacetone by Aspergillus species.
Asakawa Y, et al.
Phytochemistry, 30(12), 3981-3987 (1991)
Michael F Russell et al.
Phytochemistry, 62(5), 683-689 (2003-03-07)
Individual leaves of the three most common chemotypes of Melaleuca alternifolia were examined both quantitatively and qualitatively for volatile constituents from the emergence of the first true leaves, through to 6-week-old tenth leaf set material. The 1,8-cineole and terpinolene chemotypes
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