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I5605

Sigma-Aldrich

Indoline

ReagentPlus®, 99%

Sinónimos:

1-Azaindan, 2,3-Dihydroindole

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About This Item

Fórmula empírica (notación de Hill):
C8H9N
Número de CAS:
496-15-1
Peso molecular:
119.16
Beilstein/REAXYS Number:
111915
EC Number:
207-816-8
MDL number:
MFCD00005705
UNSPSC Code:
12352100
PubChem Substance ID:
24896074
NACRES:
NA.22

product line

ReagentPlus®

assay

99%

form

liquid

refractive index

n20/D 1.592 (lit.)

bp

220-221 °C (lit.)

density

1.063 g/mL at 25 °C (lit.)

SMILES string

C1Cc2ccccc2N1

InChI

1S/C8H9N/c1-2-4-8-7(3-1)5-6-9-8/h1-4,9H,5-6H2

InChI key

LPAGFVYQRIESJQ-UHFFFAOYSA-N

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Application

Reactant for preparation of:
  • Inhibitors of NOD1-Induced Nuclear Factor-κB Activation
  • Sphingosine-1-phosphate 4(S1P4) receptor antagonists
  • Cytotoxic cell cycle inhibitors
  • 2-Aminopyridines
  • PET agent for imaging of protein kinase C (PKC)
  • Sodium-dependent glucose co-transporter 2 (SGLT2) inhibitors for the management of hyperglycemia in diabetes
  • α4β2-Nicotinic acetylcholine receptor-selective partial agonists
  • mGlu4 positive allosteric modulators
  • Bacterial biofilm inhibitors
  • Serotonin 5-HT6 receptor antagonists

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

199.4 °F - closed cup

flash_point_c

93 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Indoline-2-carboxylic acid 97%

Sigma-Aldrich

302244

Indoline-2-carboxylic acid

N-Methylisatoic anhydride technical, 90%

Sigma-Aldrich

129887

N-Methylisatoic anhydride

Matej Baláž et al.
Molecules (Basel, Switzerland), 24(18) (2019-09-22)
Performing solution-phase oximation reactions with hydroxylamine hydrochloride (NH2OH·HCl) carries significant risk, especially in aqueous solutions. In the present study, four N-substituted indole-3-carboxaldehyde oximes were prepared from the corresponding aldehydes by solvent-free reaction with NH2OH·HCl and a base (NaOH or Na2CO3)
Toshiharu Noji et al.
Organic letters, 15(8), 1946-1949 (2013-04-04)
A benzyne-mediated synthesis of substituted indolines and carbazoles was developed. The reaction includes generation of benzyne using Mg(TMP)2·2LiCl as a base, cyclization, and trapping the resulting organomagnesium intermediate with an electrophile to provide a series of substituted indolines and carbazoles
Tanguy Saget et al.
Organic letters, 15(6), 1354-1357 (2013-03-05)
The synthesis of cyclopropyl spiroindolines is described using an intramolecular palladium(0)-catalyzed C-H functionalization of a methine C(sp(3))-H bond. This transformation can be coupled with intermolecular Suzuki couplings or direct arylations of heteroaromatics to access functionalized indoline scaffolds in a single
Ke Chen et al.
Organic & biomolecular chemistry, 10(32), 6600-6606 (2012-07-17)
A palladacycle-catalyzed tandem Heck-intramolecular aza-Michael reaction protocol has been developed for the one-pot synthesis of 1-substituted isoindolines from N-unprotected 2-bromobenzylamines and acrylates with high yields.
A diversity-oriented approach to spiroindolines: post-Ugi gold-catalyzed diastereoselective domino cyclization.
Sachin G Modha et al.
Angewandte Chemie (International ed. in English), 51(38), 9572-9575 (2012-08-22)
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