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Merck

713171

Sigma-Aldrich

1-Ethyl-1-methylpyrrolidinium bromide

99%

Sinónimos:

N-Ethyl-N-methylpyrrolidinium bromide, [EMPyrr]Br

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About This Item

Fórmula empírica (notación de Hill):
C7H16BrN
Número de CAS:
Peso molecular:
194.11
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

≥98.5% (T)
99%

form

powder

impurities

≤1.0% water

SMILES string

[Br-].CC[N+]1(C)CCCC1

InChI

1S/C7H16N.BrH/c1-3-8(2)6-4-5-7-8;/h3-7H2,1-2H3;1H/q+1;/p-1

InChI key

KHJQQUGSPDBDRM-UHFFFAOYSA-M

General description

1-Ethyl-1-methylpyrrolidinium bromide is an ionic liquid that can be prepared by reacting N-methylpyrrolidine with bromoethane. it is conventionally used as a bromine-sequestering agent (BSA) in zinc/bromine redox flow batteries.

Application

1-Ethyl-1-methylpyrrolidinium bromide may be used in the preparation of 1-ethyl-1-methylpyrrolidinium lactate, a potential solvent for the separation of hexan-1-ene from hexane. It can also be used to prepare 1-ethyl-1-methylpyrrolidinium tribromide. It can be used as a co-catalyst during the cycloaddition of CO2 with different epoxides to form cyclic carbonates in the presence of a nona-vacant Keggin-type tricarbonyl rhenium derivative catalyst.

pictograms

Health hazard

signalword

Warning

hcodes

pcodes

Hazard Classifications

Muta. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Visite la Librería de documentos

Structural characterization of novel ionic salts incorporating trihalide anions.
Dean PM, et al.
Australian Journal of Chemistry, 62(4), 334-340 (2009)
Effect of ionic liquids on the dispersion of zinc oxide and silica nanoparticles, vulcanisation behaviour and properties of NBR composites
Maciejewska, M., and M. Zaborski.
Express Polymer Letters, 8.12 (2014)
The influence of ionic liquid additives on zinc half-cell electrochemical performance in zinc/bromine flow batteries.
Rajarathnam GP, et al.
Royal Society of Chemistry Advances, 6(33), 27788-27797 (2016)
Estimation of State-of-Charge for Zinc-Bromine Flow Batteries by In Situ Raman Spectroscopy
Lee, Hyun Ju, Dong-Won Kim, and Jung Hoon Yang
Journal of the Electrochemical Society, 164.4, A754-A759 (2017)
Base stable pyrrolidinium cations for alkaline anion exchange membrane applications
Gu, Fenglou, et al.
Macromolecules, 47.19, 6740-6747 (2014)

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