693065

R-BINAP

• Sinónimos: (R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphyl, (R)-(+)-BINAP
• Fórmula lineal: [(C₆H₅)₂PC₁₀H₆-]₂
• Número de CAS: 76189-55-4
• Peso molecular: 622.67
• MDL number: MFCD00010805
• UNSPSC Code: 12352005
• PubChem Substance ID: 329761559
• NACRES: NA.22

Propiedades

• form: crystals
• optical activity: [α]20/D +222°, c = 0.5% in benzene
• mp: 239-241 °C (lit.)
• SMILES string: c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
• InChI: 1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
• InChI key: MUALRAIOVNYAIW-UHFFFAOYSA-N

Descripción

Application

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-BINAP reacts with allylpalladium(II) chloride dimer to form a BINAP-palladium catalyst, which can catalyze the asymmetric allylation of 1,3-diketones to form chiral 2,2-dialkyl-1,3-diketones. It may also be used in the preparation of chirally stabilized rhodium nanoparticles, which can be used as a catalyst for the asymmetric hydroformylation of styrene and vinyl acetate.

Legal Information

Sold in collaboration with Takasago for research purposes only.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)