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524670

Sigma-Aldrich

Luperox® DHD-9, 2-Butanone peroxide solution

~32 wt. % in phthalate-free plasticizer mixture

Sinónimos:

2-Butanone peroxide solution, Methyl ethyl ketone peroxide solution

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About This Item

Fórmula lineal:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
Número de CAS:
1338-23-4
Peso molecular:
210.22
Beilstein/REAXYS Number:
1759757
MDL number:
MFCD00042641
UNSPSC Code:
12162002
PubChem Substance ID:
24874434
NACRES:
NA.23

Quality Level

100

reaction suitability

reagent type: oxidant

concentration

~32 wt. % in phthalate-free plasticizer mixture

refractive index

n20/D 1.437

density

0.99 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI key

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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Categorías relacionadas

Application

Polymerization initiator

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Org. Perox. D - Repr. 2 - Skin Corr. 1B

Storage Class

5.2 - Organic peroxides and self-reacting hazardous materials

wgk_germany

WGK 1

flash_point_f

165.2 °F - closed cup

flash_point_c

74 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
MKCV6835
MKCW1945
MKCW9542
MKCV3733
MKCT0678

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Ron-Hsin Chang et al.
Journal of hazardous materials, 141(3), 762-768 (2006-09-05)
In Taiwan, Japan, and China, methyl ethyl ketone peroxide (MEKPO) has caused many severe thermal explosions owing to its thermal instability and reactivity originating from the complexity of its structure. This study focused on the incompatible features of MEKPO as
[Caustic esophago-gastric and liver lesions caused by ingestion of a plastic resin hardener].
M Blazquez et al.
Gastroenterologie clinique et biologique, 15(6-7), 554-555 (1991-01-01)
Jen-Hao Chi et al.
Journal of hazardous materials, 171(1-3), 1145-1149 (2009-07-22)
In the past, process incidents attributed to organic peroxides (OPs) that involved near misses, over-pressures, runaway reactions, and thermal explosions occurred because of poor training, human error, incorrect kinetic assumptions, insufficient change management, and inadequate chemical knowledge in the manufacturing
D L Warren et al.
Archives of biochemistry and biophysics, 285(1), 45-52 (1991-02-15)
Since experiments with freshly isolated rat hepatocytes have shown that cellular vitamin E is consumed in response to insult by compounds that induce an oxidative stress only after cellular glutathione (GSH) concentrations have been substantially depleted, experiments were performed to
C C G van Enckevort et al.
Clinical toxicology (Philadelphia, Pa.), 46(1), 74-78 (2008-01-02)
The plastic hardener methyl ethyl ketone peroxide (MEKP) is an unstable peroxide that releases free oxygen radicals. Ingestion of this compound induces widespread liver necrosis that is often fatal, extensive ulceration with subsequent scarring, and stenosis of the proximal digestive
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