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497312

Sigma-Aldrich

4-Piperidinemethanol

97%

Sinónimos:

4-(Hydroxymethyl)piperidine

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About This Item

Fórmula empírica (notación de Hill):
C6H13NO
Número de CAS:
6457-49-4
Peso molecular:
115.17
MDL number:
MFCD00174228
UNSPSC Code:
12352100
PubChem Substance ID:
24873109
NACRES:
NA.22

assay

97%

bp

118-120 °C/10 mmHg (lit.)

mp

55-59 °C (lit.)

SMILES string

OCC1CCNCC1

InChI

1S/C6H13NO/c8-5-6-1-3-7-4-2-6/h6-8H,1-5H2

InChI key

XBXHCBLBYQEYTI-UHFFFAOYSA-N

Categorías relacionadas

General description

4-Piperidinemethanol is a cyclic secondary amine. Its standard molar enthalpies of combustion, sublimation and formation have been determined.

application

4-Piperidinemethanol may be used in the preparation of:
  • N-tert-butoxycarbonyl-4-hydroxymethyl piperidine
  • desferrioxamine B (DFO) containing third generation triazine dendrimer
  • ethyl 3-(4-(hydroxymethyl)piperidin-1-yl)propanoate (EHMPP)
  • 4-(hydroxymethyl)piperidine-1-carbodithioic acid (HL)
  • 1-[[(1E)-2-(4-chlorophenyl)ethenyl]sulfonyl]-4-piperidinemethanol
Substrate used in solid-phase organic synthesis of a secondary amine.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análisis (COA)

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Sigma-Aldrich

715662

3-Methylamino-1-propanol

Ethyl isonipecotate 98%

Sigma-Aldrich

E33505

Ethyl isonipecotate

4-Pyridinemethanol 99%

Sigma-Aldrich

151629

4-Pyridinemethanol

Christian A Olsen et al.
Organic letters, 6(12), 1935-1938 (2004-06-05)
[reaction: see text] An expedient solid-phase synthetic approach to secondary and tertiary amines was developed. The protocol employs conversion of resin-bound amino alcohols to the corresponding iodides, followed by iodide displacement with primary or secondary amines or with unprotected amino
Synthesis, spectroscopy, and biological activity of heterobimetallic complexes containing Sn (IV) and Pd (II) with 4-(hydroxymethyl) piperidine-1-carbodithioic acid.
Anwar MT, et al.
Russ. J. Gen. Chem., 83(12), 2380-2385 (2013)
Jongdoo Lim et al.
Bioorganic & medicinal chemistry, 18(15), 5749-5753 (2010-07-10)
The synthesis of a third generation triazine dendrimer, 1, containing multiple, iron-sequestering desferrioxamine B (DFO) groups is described. Benzoylation of the hydroxamic acid groups of DFO and formation of a reactive dichlorotriazine provide the intermediate for reaction with the second
Francis Giraud et al.
Bioorganic & medicinal chemistry letters, 19(2), 301-304 (2008-12-19)
Continuous efforts on the synthesis and structure-activity relationships (SARs) studies of modified 1-benzylamino-2-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-2-ols as antifungal agents, allowed identification of new 1-[(pyridinyl- and piperidinylmethyl)amino] derivatives with MIC(80) values ranging from 1410.0 to 23.0ngmL(-1) on Candidaalbicans. These results confirmed both the importance
Standard molar enthalpies of formation of 2-, 3-, and 4-piperidinomethanol isomers.
da Silva MAVR and Cabral JITA
The Journal of Chemical Thermodynamics, 38(8), 1008-1012 (2006)
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