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430218

Sigma-Aldrich

Poly[4,4′-methylenebis(phenyl isocyanate)-alt-1,4-butanediol/di(propylene glycol)/polycaprolactone]

pellets, MDI-polyester/polyether polyurethane.

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About This Item

Número de CAS:
68084-39-9
MDL number:
MFCD00217691
UNSPSC Code:
12162002
NACRES:
NA.23

abrasion resistance

10 mg (Taber, H-22 wheel)

form

beads
pellets

melt index

4 g/10 min (190°C/8.7kg)

hardness

84 (Shore A, ASTM D 2240)

transition temp

Tg −40 °C (DSC)
softening point 85 °C (Vicat, ASTM D 1525)

density

1.18 g/mL at 25 °C (lit.)

General description

Poly[4,4′-methylenebis(phenyl isocyanate)-alt-1,4-butanediol/di(propylene glycol)/polycaprolactone] (PU/PCL) is a polyurethane solution that can be used as a shape memory polymer and a reinforcing unit for enhancing the mechanical and thermal properties of the base materials. It is biocompatible and finds usage in endothelial proliferations. PU/PCL contains polycaprolactone (PCL) that facilitates the hydrophobic properties of the polymeric matrix.

Application

Automotive fascia, cable jackets, side trim, fabric laminates, health care tubing, catheters, transdermal patches and in seals casters, shoes, bushings and wheels.
PU/PCL can be used in the formation of a polyurethane membrane for effective gas separation. It can also be used to synthesize reinforced hydrogel with good thermo-mechanical properties for biomedical applications.

Features and Benefits

Tough, high-performance, wear-resistant elastomer with good clarity, chemical resistance, flexibility and toughness. Can be used in current form or further polymerized. Low compression set

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Gas separation in mixed matrix membranes based on polyurethane containing SiO2, ZSM-5, and ZIF-8 nanoparticles
Amedi HR and Aghajani M
Journal of Natural Gas Science and Engineering, 35(19), 695-702 (2016)
Strong fiber reinforced hydrogels for biomedical applications
2011 IEEE 37th Annual Northeast Bioengineering Conference (NEBEC), 9(2), 1-2 (2011)
3D Networked Graphene-Ferromagnetic Hybrids for Fast Shape Memory Polymers with Enhanced Mechanical Stiffness and Thermal Conductivity
Lee S, et al.
Small, 10(19), 3880-3886 (2014)
Zuo-jun Hu et al.
BMC cardiovascular disorders, 12, 115-115 (2012-12-05)
In a previous in vitro study, we confirmed that small-caliber nanofibrous polyurethane (PU) vascular grafts have favorable mechanical properties and biocompatibility. In the present study, we examined the in vivo biocompatibility and stability of these grafts. Forty-eight adult male beagle
The in vivo performance of small-caliber nanofibrous polyurethane vascular grafts
Hu Z, et al.
BMC Cardiovascular Disorders, 12(1), 115-115 (2012)
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