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Merck

234893

Sigma-Aldrich

Ethyl methacrylate

contains 15-20 ppm monomethyl ether hydroquinone as inhibitor, 99%

Sinónimos:

2-Methyl-2-propenoic acid

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About This Item

Fórmula lineal:
CH2=C(CH3)COOC2H5
Número de CAS:
Peso molecular:
114.14
Beilstein/REAXYS Number:
471201
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.25

vapor density

>3.9 (vs air)

Quality Level

vapor pressure

15 mmHg ( 20 °C)

assay

99%

form

liquid

autoignition temp.

771 °F

contains

15-20 ppm monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.413 (lit.)

bp

118-119 °C (lit.)

density

0.917 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCOC(=O)C(C)=C

InChI

1S/C6H10O2/c1-4-8-6(7)5(2)3/h2,4H2,1,3H3

InChI key

SUPCQIBBMFXVTL-UHFFFAOYSA-N

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General description

Ethyl methacrylate (EMA) is a monomer commonly used in the field of polymer industries. It is an ester of methacrylic acid and ethanol and is a colorless liquid with a characteristic odor. EMA is widely used in the production of various polymers such as poly(methyl methacrylate) (PMMA), poly(ethyl acrylate) (PEA), and ethylene-EMA (EE). These polymers find their application in various fields, including medical implant devices, packaging, paper coatings, textile coatings, emulsion polymers, and plastics.

Ethyl methacrylate is a readily polymerizable monomer used for certain types of acrylic resins. The monomethyl ether hydroxyl quinone present in it is an inhibitor that prevents polymerization.

Application

Ethyl methacrylate (EMA) can be used as a monomer in the following applications:
  • To synthesize artificial nanosized latexes of poly(styrene-co-methyl methacrylate) or poly(styrene-co-ethyl methacrylate), which are in producing drug-releasing films.
  • In the production of additive-manufactured methacrylate-based resins used in dentistry.
  • In the synthesis of a star-shaped block copolymer electrolyte for all-solid-state lithium batteries.
  • In the synthesis of a copolymer used as a matrix for semiconductor nanoparticles, which is crucial for the formation of a stable matrix for the quantum dots-copolymer composite material used in optoelectronic applications.
It can also be used to prepare copolymers of EMA on waxy maize starch and hydroxypropyl starch, the potential application of these copolymers are as excipients for compressed non-disintegrating matrix tablets. It may be used to study reactions of n-butyl acrylate and EMA with ozone in the gas phase.

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

66.2 °F - closed cup

flash_point_c

19 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Reactions of n-butyl acrylate and ethyl methacrylate with ozone in the gas phase, Computational and Theoretical Chemistry
Sun Y, et al.
Computational & Theoretical Chemistry, 1039, 33-39 (2014)
Mengwei Pi et al.
Colloids and surfaces. B, Biointerfaces, 78(2), 193-199 (2010-03-30)
The nanoparticles composed of polystyrene core and poly[2-(diethylamino)ethyl methacrylate] (PDEA) hairy shell were used as colloidal templates for in situ silica mineralization, allowing the well-controlled synthesis of hybrid silica core-shell nanoparticles with raspberry-like morphology and hollow silica nanoparticles by subsequent
M B Abou-Donia et al.
Journal of toxicology and environmental health. Part A, 59(2), 97-118 (2000-02-01)
Ethyl methacrylate (ethyl 2-methyl-2-propenoate, EMA) has been implicated in the development of neurologic impairment following occupational exposure. The potential of EMA to produce neurotoxicity was investigated in adult male Sprague-Dawley rats in two experiments. In the first experiment, animals were
International journal of toxicology, 21 Suppl 1, 63-79 (2002-06-04)
Ethyl Methacrylate is a methacrylate ester used as a chemical additive in artificial fingernail enhancement products. These products may be applied by trained professionals or be provided directly to consumers with instructions for use. Ethyl Methacrylate readily polymerizes and rapidly
K C Gupta et al.
Biomacromolecules, 2(1), 239-247 (2001-12-26)
The graft copolymerization of acrylonitrile and ethyl methacrylate from their binary mixtures onto cellulose has been carried out in the presence of Ce(IV) ions in acidic media at 30 +/- 0.1 degrees C. The graft copolymerization has shown an increasing

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