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Key Documents

307254

Sigma-Aldrich

Diisopropylphosphoramidous dichloride

95%

Synonym(s):

(Diisopropylamino)dichlorophosphine, Bis(isopropyl)aminodichlorophosphine, Dichloro(diisopropylamido)phosphorus, Dichloro(diisopropylamino)phosphine

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About This Item

Linear Formula:
[(CH3)2CH]2NPCl2
CAS Number:
Molecular Weight:
202.06
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:

Assay

95%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.485 (lit.)

density

1.096 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(C)N(C(C)C)P(Cl)Cl

InChI

1S/C6H14Cl2NP/c1-5(2)9(6(3)4)10(7)8/h5-6H,1-4H3

InChI key

UPPVRFOGRCBSJP-UHFFFAOYSA-N

Application

Reagent for the synthesis of peptides and oligonucleotide analogues.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Pyr. Liq. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

No data available

Flash Point(C)

No data available

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Tetrahedron, 47, 2449-2449 (1991)
The Journal of Organic Chemistry, 59, 6687-6687 (1994)

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