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237051

Sigma-Aldrich

Aluminum chloride

ReagentPlus®, 99%

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About This Item

Fórmula lineal:
AlCl3
Número de CAS:
7446-70-0
Peso molecular:
133.34
Número CE:
231-208-1
Número MDL:
MFCD00003422
Código UNSPSC:
12352302
eCl@ss:
38120507
ID de la sustancia en PubChem:
329752441
NACRES:
NA.21
En este momento no podemos mostrarle ni los precios ni la disponibilidad

grado

reagent

presión de vapor

1 mmHg ( 100 °C)

Línea del producto

ReagentPlus®

Ensayo

99%

Formulario

powder

idoneidad de la reacción

reagent type: catalyst
core: aluminum

pH

2.4 (20 °C, 100 g/L)

mp

190 °C (lit.)

cadena SMILES

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

Clave InChI

VSCWAEJMTAWNJL-UHFFFAOYSA-K

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Categorías relacionadas

Descripción general

Aluminum chloride is an alcohol-soluble lewis acid.† Aluminum chloride mixed with sodium borohydride, in diglyme in a molar ratio affords a mixture having strong reducing properties.† It was reported to promote the Friedel-Crafts acylation reaction between 4-tert-butylbenzoyl chloride and mesitylene.†

Aplicación

Aluminum chloride was used for the following studies:
  • Polymerization of benzene to afford p-polyphenyl.[1]
  • As a catalyst for the Friedel-Crafts acylation of buckymetallocenes with the acid chlorides.[2]
  • As a catalyst for the colorimetric microassay for the determination of lipid hydroperoxides.[3]

Características y beneficios

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.

Información legal

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

Corrosion
GHS05

Palabra de señalización

Danger

Frases de peligro

H314

Clasificaciones de peligro

Eye Dam. 1 - Skin Corr. 1B

Riesgos supl.

EUH014,EUH071

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
BCCM8520
SDBB1971
STBL1998
STBL0490
STBK7612

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Visite la Librería de documentos

Detection of Alternative Oxidase Expression in Arabidopsis thaliana Protoplasts Treated with Aluminium.
Liu J, et al.
Bio-protocol, 5(13) (2015)
Shutao Wang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(4), 1700712-1700712 (2018-05-04)
In the search for low-cost and large-scale stationary storage of electricity, nonaqueous aluminum chloride-graphite batteries (AlCl3-GBs) have received much attention due to the high natural abundances of their primary constituents, facile manufacturing, and high energy densities. Much research has focused
Yutaka Matsuo et al.
Dalton transactions (Cambridge, England : 2003), 43(20), 7407-7412 (2013-10-26)
Acylated buckyferrocene and ruthenocene, Fe(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me, Ph, and CH[double bond, length as m-dash]CHPh) and Ru(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in
Rajkumar Kore et al.
Dalton transactions (Cambridge, England : 2003), 47(23), 7795-7803 (2018-06-01)
Two solids of differing Lewis acidities, triethylammonium tetrachlorozincate ([HN222]2[ZnCl4]) and AlCl3, have been combined across 0.1 to 0.9 mole fractions (with respect to [HN222]2[ZnCl4]), and homogeneous solid double salts or mixed metal [HN222]2x[(1 - x)AlCl3 + xZnCl4] double salt ionic
p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
Kovacic P and Oziomek J.
The Journal of Organic Chemistry, 29(1), 100-104 (1964)
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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