237051
Aluminum chloride
ReagentPlus®, 99%
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About This Item
Fórmula lineal:
AlCl3
Número de CAS:
Peso molecular:
133.34
Número CE:
Número MDL:
Código UNSPSC:
12352302
eCl@ss:
38120507
ID de la sustancia en PubChem:
NACRES:
NA.21
Ensayo:
99%
Formulario:
powder
Productos recomendados
presión de vapor
1 mmHg ( 100 °C)
Nivel de calidad
Línea del producto
ReagentPlus®
Ensayo
99%
Formulario
powder
idoneidad de la reacción
reagent type: catalyst
core: aluminum
pH
2.4 (20 °C, 100 g/L)
mp
190 °C (lit.)
cadena SMILES
Cl[Al](Cl)Cl
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
Clave InChI
VSCWAEJMTAWNJL-UHFFFAOYSA-K
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Categorías relacionadas
Descripción general
Aluminum chloride is an alcohol-soluble lewis acid.† Aluminum chloride mixed with sodium borohydride, in diglyme in a molar ratio affords a mixture having strong reducing properties.† It was reported to promote the Friedel-Crafts acylation reaction between 4-tert-butylbenzoyl chloride and mesitylene.†
Aplicación
Aluminum chloride was used for the following studies:
- Polymerization of benzene to afford p-polyphenyl.
- As a catalyst for the Friedel-Crafts acylation of buckymetallocenes with the acid chlorides.
- As a catalyst for the colorimetric microassay for the determination of lipid hydroperoxides.
Características y beneficios
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.
Información legal
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Palabra de señalización
Danger
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Eye Dam. 1 - Skin Corr. 1B
Riesgos supl.
Código de clase de almacenamiento
8A - Combustible corrosive hazardous materials
Clase de riesgo para el agua (WGK)
WGK 1
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
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Acylated buckyferrocene and ruthenocene, Fe(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me, Ph, and CH[double bond, length as m-dash]CHPh) and Ru(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in
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p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
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