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90479

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Glyphosate-2-13C,15N

PESTANAL®, analytical standard

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About This Item

Fórmula lineal:
HO2C13CH215NHCH2PO3H2
Número de CAS:
285978-24-7
Peso molecular:
171.06
Número MDL:
MFCD01075407
Código UNSPSC:
77101502
ID de la sustancia en PubChem:
329769915
NACRES:
NA.24

grado

analytical standard

Nivel de calidad

200

Línea del producto

PESTANAL®

Ensayo

≥99% (HPLC)

caducidad

limited shelf life, expiry date on the label

impurezas

≤0.5% water

mp

230 °C (dec.) (lit.)

aplicaciones

agriculture
environmental

Formato

neat

cambio de masa

M+2

cadena SMILES

OC(=O)[13CH2][15NH]CP(O)(O)=O

InChI

1S/C3H8NO5P/c5-3(6)1-4-2-10(7,8)9/h4H,1-2H2,(H,5,6)(H2,7,8,9)/i1+1,4+1

Clave InChI

XDDAORKBJWWYJS-VFZPYAPFSA-N

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Descripción general

Glyphosate is one of the most used herbicides, especially in agriculture applications such as weed and vegetation control.

Aplicación

Glyphosate-2-13C,15N may be used as a reference standard for the determination of glyphosate-2-13C,15N in saline natural water samples by high-performance liquid chromatography coupled to tandem mass spectrometry (HPLC-MS/MS). It may also be used as an internal standard for the analysis of glyphosate, aminomethylphosphonic acid and glufosinate in water samples by online solid-phase extraction (SPE) followed by HPLC/MS.

Nota de análisis

13C enrichment ≥99 atom% based upon labeld precursor
15N enrichment ≥98 atom% based upon labeld precursor

Información legal

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Palabra de señalización

Danger

Frases de peligro

H312,H318,H411

Clasificaciones de peligro

Acute Tox. 4 Dermal - Aquatic Chronic 2 - Eye Dam. 1

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
BCCL9604
BCCJ4513
BCCG3972
BCCB5290
BCBZ3625

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Methods of analysis by the US geological survey organic geochemistry research group-determination of glyphosate, aminomethylphosphonic acid, and glufosinate in water using online solid-phase extraction and high-performance liquid chromatography/mass spectrometry
Lee EA, et al.
Journal of Chromatography and Separation Techniques, 7(338), 2-2 (2002)
Optimization of an Enrichment and LC-MS/MS Method for the Analysis of Glyphosate and Aminomethylphosphonic Acid (AMPA) in Saline Natural Water Samples without Derivatization
Pupke D, et al.
Journal of Chromatography and Separation Techniques, 7(338), 2-2 (2016)
Lene Nørby Nielsen et al.
Environmental pollution (Barking, Essex : 1987), 233, 364-376 (2017-11-03)
Recently, concerns have been raised that residues of glyphosate-based herbicides may interfere with the homeostasis of the intestinal bacterial community and thereby affect the health of humans or animals. The biochemical pathway for aromatic amino acid synthesis (Shikimate pathway), which

Artículos

LC/MS/MS Method for Determination of Glyphosate, AMPA, and Glufosinate in Cereals

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

LC/MS/MS Method for Determination of Glyphosate, AMPA, and Glufosinate in Cereals

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

LC/MS/MS Method for Determination of Glyphosate, AMPA, and Glufosinate in Cereals

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

LC/MS/MS Method for Determination of Glyphosate, AMPA, and Glufosinate in Cereals

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

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