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Merck

46001

Supelco

Benoxacor

PESTANAL®, analytical standard

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About This Item

Fórmula empírica (notación de Hill):
C11H11Cl2NO2
Número de CAS:
Peso molecular:
260.12
Beilstein/REAXYS Number:
4190275
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CC1COc2ccccc2N1C(=O)C(Cl)Cl

InChI

1S/C11H11Cl2NO2/c1-7-6-16-9-5-3-2-4-8(9)14(7)11(15)10(12)13/h2-5,7,10H,6H2,1H3

InChI key

PFJJMJDEVDLPNE-UHFFFAOYSA-N

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Categorías relacionadas

General description

Benoxacor is a dichloroacetamide herbicide safener, used to protect corn against injury from metolachlor. Its role as a safener involves inducing the enzymatic mechanism of chloroacetanilide detoxification in plants.

Application

Benoxacor may be used as a reference standard in the determination of benoxacor in wheat and soil samples using gas chromatography (GC) and high performance liquid chromatography (HPLC).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Chronic 1 - Skin Sens. 1

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type N95 (US)


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Certificados de análisis (COA)

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Sihong Liu et al.
The Science of the total environment, 761, 143273-143273 (2020-11-17)
Benoxacor, a chiral herbicide safener for S-metolachlor, has been detected in streams. However, the potential risk this poses to aquatic ecosystems is not clear. This study used zebrafish (Danio rerio) embryos as a model to assess the enantioselective toxicity of
G Kocsy et al.
Plant physiology, 127(3), 1147-1156 (2001-11-14)
With the aim of analyzing their protective function against chilling-induced injury, the pools of glutathione and its precursors, cysteine (Cys) and gamma-glutamyl-Cys, were increased in the chilling-sensitive maize (Zea mays) inbred line Penjalinan using a combination of two herbicide safeners.
Daniele Del Buono et al.
Journal of agricultural and food chemistry, 53(11), 4326-4330 (2005-05-26)
Butachlor is a chloroacetanilide herbicide successfully employed in weeding some important crops, and benoxacor is a safening compound able to induce the enzymatic mechanism of chloroacetanilide detoxification in plants. A practical method for a simultaneous detection of butachlor and benoxacor
Purification and characterization of a glutathione S-transferase from benoxacor-treated maize (Zea mays).
Irzyk PG and Fuerst PE
Plant Physiology, 102(3), 803-810 (1993)
Aaron P Smith et al.
The Journal of biological chemistry, 279(25), 26098-26104 (2004-04-08)
Glutathione S-transferases (GSTs) are involved in many stress responses in plants, for example, participating in the detoxification of xenobiotics and limiting oxidative damage. Studies examining the regulation of this gene family in diverse plant species have focused primarily on RNA

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