ALD00288

Sodium tert-butylsulfinate

• Sinónimos: TBS-Na
• Fórmula empírica (notación de Hill): C₄H₉NaO₂S
• Número de CAS: 69152-35-8
• Peso molecular: 144.17
• UNSPSC Code: 41106514
• PubChem Substance ID: 329772648
• NACRES: NA.22

Propiedades

• form: solid
• Quality Level: 100
• reaction suitability: reaction type: C-C Bond Formation; reagent type: catalyst; reaction type: C-H Activation
• SMILES string: CC(C)(C)S(O[Na])=O
• InChI: 1S/C4H10O2S.Na/c1-4(2,3)7(5)6;/h1-3H3,(H,5,6);/q;+1/p-1
• InChI key: VOHJOJMSAGPWBW-UHFFFAOYSA-M

Descripción

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H319
• pcodes: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable