756792
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane
97%
Sinónimos:
DAPTA
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About This Item
Fórmula empírica (notación de Hill):
C9H16N3O2P
Número de CAS:
Peso molecular:
229.22
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
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assay
97%
form
solid
mp
183 °C (decomposition)
SMILES string
CC(=O)N1CN2CN(CP(C2)C1)C(C)=O
InChI
1S/C9H16N3O2P/c1-8(13)11-3-10-4-12(9(2)14)7-15(5-10)6-11/h3-7H2,1-2H3
InChI key
MYJHMDGWZWBLCK-UHFFFAOYSA-N
Application
3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane is a phosphine ligand and acetylized derivative of 1,3,5-triaza-7-phosphaadamantane that can be used:
- As a ligand in the synthesis of diiron dithiolate complexes of Fe-only hydrogenase to improve the hydro- and protophilicity of the active site.
- To prepare (η6-arene)-ruthenium(II) complex, which is employed as a catalyst in the reduction of allylic alcohols.
- As a ligand in the synthesis of water-soluble cis- and trans-Pt(II) and Pd(II) metal complexes.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificados de análisis (COA)
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Na Y, et al.
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Synthesis and characterization of Pt(II) and Pd(II) PTA and DAPTA complexes
Braddock-Wilking J, et al.
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