665096

Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)

97%

• Sinónimos: Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
• Fórmula empírica (notación de Hill): C₂₀H₂₁Cl₃O₂PReS
• Número de CAS: 108695-90-5
• Peso molecular: 648.98
• MDL number: MFCD08276862
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884712
• NACRES: NA.22

Propiedades

• assay: 97%
• form: powder
• reaction suitability: core: rhenium; reagent type: catalyst
• SMILES string: CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
• Inchi Key: GIBDGLAUIKUJJX-UHFFFAOYSA-K

Descripción

Application

Catalyst for:

• Enantioselective reduction of ketones and imines
• Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
• Synthesis of 2-deoxy-α glycosides
• Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds

Reagent for rhenium-cyclized somatostatine derivative series synthesis

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves