640360

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

• Sinónimos: [Rh(cod)(MeCN)₂]BF₄
• Fórmula empírica (notación de Hill): C₁₂H₁₈BF₄N₂Rh
• Número de CAS: 32679-02-0
• Peso molecular: 379.99
• MDL number: MFCD06798085
• UNSPSC Code: 12161600
• PubChem Substance ID: 24883086
• NACRES: NA.22

Propiedades

• form: solid
• reaction suitability: core: rhodium; reagent type: catalyst
• SMILES string: [Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1
• InChI: 1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;
• InChI key: KSMAFOANQHYEJG-SUESZSCISA-N

Descripción

Application

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)₂]BF₄ may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone.

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves