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50790

Sigma-Aldrich

Cloruro de oro(III) hydrate

~50% Au basis

Sinónimos:

Cloruro áurico, Tetracloroaurato (III) de hidrógeno hydrate, Ácido cloroáurico, Ácido tetracloroáurico (III)

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About This Item

Fórmula lineal:
HAuCl4 · aq
Número de CAS:
27988-77-8
Peso molecular:
339.79 (anhydrous basis)
Número CE:
240-948-4
Número MDL:
MFCD00149903
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
57651272
NACRES:
NA.23
En este momento no podemos mostrarle ni los precios ni la disponibilidad

Nivel de calidad

100

Formulario

powder or crystals

concentración

~50% Au

color

yellow

densidad

3.9 g/mL at 25 °C

cadena SMILES

O.Cl.Cl[Au](Cl)Cl

InChI

1S/Au.4ClH.H2O/h;4*1H;1H2/q+3;;;;;/p-3

Clave InChI

OVJUDSKPNIBLOO-UHFFFAOYSA-K

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Descripción general

Gold (III) chloride hydrate,also known as chloroauric acid, is used as precursor to synthesize gold nanoparticles. It also exihibits very high catalytic activity.

Aplicación

Used as a catalyst in asymmetric aldol reactions, diboration of vinylarenes, dehydrogenative dimerizations of trialkystannanes, carbonylation of olefins and amines, C-C, C-O bond couplings, oxidation of sulfides, selective oxidation of thioethers.[1][2]

Palabra de señalización

Danger

Frases de peligro

H290,H302,H314,H373,H411

Clasificaciones de peligro

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT RE 2 Oral

Órganos de actuación

Kidney

Código de clase de almacenamiento

8B - Non-combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
BCCL9313
BCCM6255
BCCM3940
BCCL2742
BCCK9338

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Raquel Casado et al.
Journal of the American Chemical Society, 125(39), 11925-11935 (2003-09-25)
Different inorganic and organometallic gold(III) and gold(I) complexes have been tested in the addition of water and methanol to terminal alkynes. Anionic and neutral organometallic gold(III) compounds can efficiently mediate these reactions in neutral media in refluxing methanol. The compounds
The crystal structure of gold (III) chloride
Acta Crystallographica, 11(4), 248-288 (1958)

Artículos

Gold Nanorod Synthesis

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

Gold Nanorod Synthesis

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

Gold Nanorod Synthesis

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

Gold Nanorod Synthesis

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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